1. chem960
  2. 102518-79-6
Introduction

石杉碱甲((-)-Huperzine A),标准命名法名称(5R,9R,11E)-5-氨基-11-乙叉基-5,6,9,10-四氢-7-甲基-5,9-甲撑环辛并(B)吡啶-2(1H)酮,是一种能有效预防中老年人脑神经衰弱、恢复脑神经功能、活化脑神经传递物质,是目前治疗良性记忆障碍的新药。石杉碱甲不仅通过抑制胆碱酯酶活性,还可以通过影响自由基系统,降低生长抑素、细胞内[Ca2+]、谷氨酸含量,提高钙调蛋白(CaM)和钙调蛋白的信使核糖核酸(CaM mRNA)表达水平等多种药理机制,提高认知功能和学习记忆能力。

Names and Identifiers
  • (-)-Huperzine A
  • 5r-(5-alpha,9-beta,11e))-ydro-7-methyl
  • 5,9-methanocycloocta(b)pyridin-2(1h)-one,5-amino-11-ethylidene-5,6,9,10-tetrah
  • HUPERIZINE
  • (-)-HUPERZINE A FROM HUPERZIA SERRATA
  • HUP, [5R-(5a,911E)]-5-Amino-11-ethylidene-5,6,9,10-tetrahydro-7-methyl-5,9-methanocycloocta[b]pyridin-2-(1H)-one, Selagine,
  • 5,9-Methanocyclooctabpyridin-2(1H)-one, 5-amino-11-ethylidene-5,6,9,10-tetrahydro-7-methyl-, (5R,9R,11E)-
  • (−)-Huperzine A
  • (5R,9R,E)-5-Amino-11-ethylidene-7-methyl-5,6,9,10-tetrahydro-5,9-methanocycloocta[b]pyridin-2(1H)-one
  • Huperzine A
  • Huperzine-A
  • Hyaluronic acid disaccharide ΔDiHA, sodium salt
  • Huperzia Serrate P.E.
  • (?)-Huperzine A
  • (?)-Selagine
  • (-)-Selagine
  • Selagine
  • [ "Selagine" ]
  • Haboyin
  • Hupzine A
  • Kimpukan A
  • Isoselagine
  • Huperizine A
  • HUPERZINE A(P)
  • Chinese Lobelia Herb Extract
  • HUPERZINE A 1%
  • (-)-huperazine A
  • HupA
  • Hup A
  • DSSTox_RID_81302
  • DSSTox_CID_26038
  • DSSTox_GSID_46038
  • Huperzine
  • HuperzineA
  • 0111871I23
  • (-)-Huperzine-A
  • (+)-Huperzine A
  • (-)-Huperzine A (H
  • LSM-5567
  • FT-0627095
  • BCBcMAP01_000072
  • KBioGR_001698
  • HMS2052D07
  • CCG-101168
  • MLS001424307
  • SPBio_000789
  • Q27166443
  • (-)- HUPPERZINE A
  • Spectrum3_001074
  • NC00418
  • CHEMBL4515144
  • Spectrum4_001229
  • C15H18N2O
  • Spectrum5_001701
  • (1R,9R,13Z)-1-Amino-13-ethylidene-11-methyl-6-azatricyclo[7.3.1.02,7]trideca-2(7),3,10-trien-5-one
  • HB0001
  • SR-01000781266
  • BCP08891
  • SMR000469231
  • KBio3_001908
  • SCHEMBL16789797
  • EX-A282
  • AC-488
  • (1R,9S,13E)-1-Amino-13-ethylidene-11-methyl-6-azatricyclo[7.3.1.02,7]trideca-2(7),3,10-trien-5-one
  • SMP1_000153
  • 120786-18-7
  • SR-01000781266-4
  • BSPBio_002688
  • (-)-huperzine A
  • C90354
  • Fordine
  • 92138-20-0
  • Spectrum2_000835
  • (1R,9R)-1-amino-13-ethylidene-11-methyl-6-azatricyclo[7.3.1.02,7]trideca-2(7),3,10-trien-5-one
  • SR-01000781266-3
  • 102518-79-6
  • Q425198
  • BRD-K62240499-001-02-6
  • UNII-0111871I23
  • (5R,9R,11E)-5-amino-11-ethylidene-7-methyl-5,6,9,10-tetrahydro-5,9-methanocycloocta[b]pyridin-2(1H)-one
  • 1369-64-8
  • SCHEMBL136368
  • 1vot
  • SPECTRUM1505255
  • BDBM50199522
  • Tox21_111603_1
  • (5R,9R,11E)-5-AMINO-11-ETHYLIDENE-5,6,9,10-TETRAHYDRO-7-METHYL-5,9-METHANOCYCLOOCTA(B)PYRIDIN-2(1H)-ONE
  • 1-amino-13-ethylidene-11-methyl-6-azatricyclo[7.3.1.0~2,7~]trideca-2(7),3,10-trien-5-one
  • (huperazine A)(-)-1-Amino-13-ethylidene-11-methyl-6-aza-tricyclo[7.3.1.0*2,7*]trideca-2(7),3,10-trien-5-one
  • Cerebra
  • 1-Amino-13-eth-(Z)-ylidene-11-methyl-6-aza-tricyclo[7.3.1.0*2,7*]trideca-2(7),3,10-trien-5-one
  • HUPERZINE A [MI]
  • CCG-40292
  • (R)-1-Amino-13-eth-(E)-ylidene-11-methyl-6-aza-tricyclo[7.3.1.0*2,7*]trideca-2(7),3,10-trien-5-one
  • 5,9-Methanocycloocta(b)pyridin-2(1H)-one, 5-amino-11-ethylidene-5,6,9,10-tetrahydro-7-methyl-, (5R-(5-alpha,9-beta,11E))-
  • HUPERZINE A [WHO-DD]
  • Q-100029
  • CHEBI:78330
  • L-huperzine A
  • HUP
  • EN300-33171546
  • NCGC00159362-02
  • Hyperazzine A
  • (-)1-Amino-13-ethylidene-11-methyl-6-aza-tricyclo[7.3.1.0*2,7*]trideca-2(7),3,10-trien-5-one( (-)-Huperzine A)
  • 5,9-Methanocycloocta(b)pyridin-2(1H)-one, 5-amino-11-ethylidene-5,6,9,10-tetrahydro-7-methyl-, (5R,9R,11E)-
  • 1-Amino-13-ethylidene-11-methyl-6-aza-tricyclo[7.3.1.0*2,7*]trideca-2(7),3,10-trien-5-one((+/-)-Huperzine A)
  • DB04864
  • SDCCGMLS-0066755.P001
  • Huperzin A
  • (-)-HuperazineA
  • NS00023157
  • CAS-102518-79-6
  • 1-Amino-13-ethylidene-11-methyl-6-aza-tricyclo[7.3.1.0*2,7*]trideca-2(7),3,10-trien-5-one
  • 1-Amino-13-eth-(E)-ylidene-11-methyl-6-aza-tricyclo[7.3.1.0*2,7*]trideca-2(7),3,10-trien-5-one
  • DTXCID6026038
  • (1R,9R)-1-Amino-13-eth-(E)-ylidene-11-methyl-6-aza-tricyclo[7.3.1.0*2,7*]trideca-2(7),3,10-trien-5-one
  • (+-)-HA
  • HUPERAINE A
  • CHEBI:94624
  • H1700
  • HUPERZINE A [VANDF]
  • (R)-1-Amino-13-ethylidene-11-methyl-6-aza-tricyclo[7.3.1.0*2,7*]trideca-2(7),3,10-trien-5-one
  • DTXSID8046038
  • (1R,9R,13E)-1-amino-13-ethylidene-11-methyl-6-azatricyclo[7.3.1.0,2,7]trideca-2(7),3,10-trien-5-one
  • AS-15723
  • 5,9-Methanocycloocta[b]pyridin-2(1H)-one, 5-amino-11-ethylidene-5,6,9,10-tetrahydro-7-methyl-, (5R,9R,11E)-
  • (-)-1-Amino-13-ethylidene-11-methyl-6-aza-tricyclo[7.3.1.0*2,7*]trideca-2(7),3,10-trien-5-one(Huperzine A)
  • 1-Amino-13-ethylidene-11-methyl-6-aza-tricyclo[7.3.1.0*2,7*]trideca-2(7),3,10-trien-5-one((-)-Huperzine A)
  • CHEMBL395280
  • Tox21_111603
  • NCGC00263655-01
  • AKOS016842839
  • (1S,13E)-1-amino-13-ethylidene-11-methyl-6-azatricyclo[7.3.1.0^{2,7}]trideca-2(7),3,10-trien-5-one
  • KBioSS_000483
  • Bio2_000882
  • 103735-86-0
  • Bio1_000660
  • Q27163539
  • (-)-Huperzine A-d5 (Major)
  • KBio2_003051
  • (+/-)Huperzine A
  • Bio2_000402
  • NCGC00163246-01
  • IDI1_002157
  • 1ST40303
  • HMS1990I05
  • KBio3_000885
  • FT-0642946
  • 1-amino-13-ethylidene-11-methyl-6-azatricyclo[7.3.1.02,7]trideca-2(7),3,10-trien-5-one
  • Bio1_000171
  • KBioGR_000483
  • BCP31534
  • LSM-1581
  • (1R,13E)-1-amino-13-ethylidene-11-methyl-6-azatricyclo[7.3.1.0^{2,7}]trideca-2(7),3,10-trien-5-one
  • (13E)-1-amino-13-ethylidene-11-methyl-6-azatricyclo[7.3.1.02,7]trideca-2(7),3,10-trien-5-one
  • KBio3_000886
  • CBiol_001885
  • 1290113-17-5
  • Bio1_001149
  • (5S,11E)-5-amino-11-ethylidene-7-methyl-5,6,9,10-tetrahydro-5,9-methanocycloocta[b]pyridin-2(1H)-one
  • BSPBio_001143
  • (+/-)-Huperzine A
  • KBio2_005619
  • (13E)-1-amino-13-ethylidene-11-methyl-6-azatricyclo[7.3.1.0^{2,7}]trideca-2(7),3,10-trien-5-one
  • CHEMBL3184073
  • KBio2_000483
  • AKOS032962044
  • BDBM10441
  • Fordine
  • (+/-)-Huperzine A
  • MDL:MFCD01714949
  • InChIKey:ZRJBHWIHUMBLCN-YQEJDHNASA-N
  • Inchi:1S/C15H18N2O/c1-3-11-10-6-9(2)8-15(11,16)12-4-5-14(18)17-13(12)7-10/h3-6,10H,7-8,16H2,1-2H3,(H,17,18)/b11-3+/t10-,15+/m0/s1
  • SMILES:O=C1C([H])=C([H])C2=C(C([H])([H])[C@]3([H])C([H])=C(C([H])([H])[H])C([H])([H])[C@]2(C3=C([H])C([H])([H])[H])N([H])[H])N1[H]
Chemical and Physical Properties

Computed Properties

  • Exact Mass: 242.32g/mol
  • Surface Charge: 0
  • XLogP3: 0
  • Hydrogen Bond Donor Count: 2
  • Hydrogen Bond Acceptor Count: 2
  • Rotatable Bond Count: 0
  • Exact Mass: 242.141913g/mol
  • Monoisotopic Mass: 242.141913g/mol
  • Topological Polar Surface Area: 55.1Ų
  • Heavy Atom Count: 18
  • Complexity: 551
  • Isotope Atom Count: 0
  • Defined Atom Stereocenter Count: 2
  • Undefined Atom Stereocenter Count: 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 1
  • Covalently-Bonded Unit Count: 1
  • 拓扑极表面积: 55.1A^2
  • 同位素原子计数: 0
  • 表面电荷: 0

Experimental Properties

  • LogP: 2.69780
  • PSA: 58.88000
  • Merck: 4755
  • 折射率: 1.626
  • 沸点: 505.0±50.0℃ at 760 mmHg
  • 熔点: 230.0 to 234.0 deg-C
  • 蒸气压: 0.0±1.3 mmHg at 25°C
  • 闪点: 259.2ºC
  • 颜色与性状: 白色至淡白色晶体粉末
  • 溶解性: 无可用
  • 最大波长(λmax): 313(EtOH)(lit.)
  • 比旋光度: -147° (c=0.36, in CH3OH)
  • 密度: 1.2 g/cm3
Security Information
  • Symbol: GHS06
  • RTECS号:PB9185700
  • WGK Germany:3
  • 安全术语:26-36/37/39-45
  • 安全说明:S26; S36/37/39; S45
  • 风险术语:R26/27/28; R36/37/38
  • 危險品標誌: T+ T+
  • 危险品运输编号:UN 1544 6.1/PG 2
  • 危害声明:H300,H310,H315,H319,H330,H335
  • 警示性声明:P260,P264,P280,P284,P301+P310,P302+P350
  • 提示语:危险
  • 储存条件:Powder -20°C 3 years   4°C 2 years In solvent -80°C 6 months   -20°C 1 month
  • PackingGroup:II
  • 危险类别码:R26/27/28;R36/37/38
  • 信号词:Danger
  • HazardClass:6.1
  • 监管条件代码:Q类 (糖类,生物碱类,抗生素类,激素类)
Customs Data
  • 海关数据:

    中国海关编码:

    2933990090

    概述:

    2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

    申报要素:

    品名, 成分含量, 用途, 乌洛托品请注明外观, 6-己内酰胺请注明外观, 签约日期

    Summary:

    2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

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J20F429756-250mg 0.95 250mg ¥10296 24 Nov. 2023
A01194066-50mg 98% 河北:3 50mg ¥384 24 Nov. 2023
A01194066-5mg 98% 河北:6 5mg ¥48 24 Nov. 2023
S18DCS-019-20mg ≥98% 20mg ¥2240 24 Nov. 2023
J82ASB-00008340-005-5mg 5mg ¥1539 24 Nov. 2023
J82ASB-00008340-050-50mg 50mg ¥9919 24 Nov. 2023
J82ASB-00008340-250-250mg 250mg ¥36427 24 Nov. 2023
J82ASB-00008340-001-1g 1g ¥109482 24 Nov. 2023
Brand:chemenu Supplier:Chemenu
No. Purity Stock Specification Price update time operate
CM247374-250mg 98% 1-2 Weeks 250mg $99/ ¥719.06 02 Mar. 2022
CM247374-100mg 98% 1-2 Weeks 100mg $51/ ¥370.42 02 Mar. 2022
Brand:麦克林 Supplier:上海麦克林生化科技有限公司
No. Purity Stock Specification Price update time operate
H875058-500mg 98% 上海仓库:现货北方仓库:非现货 500mg ¥1,918.00 13 Jan. 2022
H875058-100mg 98% 上海仓库:现货北方仓库:非现货 100mg ¥420.00 13 Jan. 2022
H875058-25mg 98% 上海仓库:现货北方仓库:现货 25mg ¥168.00 13 Jan. 2022
Brand:安捷凯 Supplier:武汉安捷凯生物医药科技有限公司
No. Purity Stock Specification Price update time operate
ajci8172-25mg 98% 现货 25mg ¥856.00 09 Sep. 2023
ajci8172-10mg 98% 现货 10mg ¥428.00 09 Sep. 2023
Brand:Acmec Supplier:上海吉至生化科技有限公司
No. Purity Stock Specification Price update time operate
H11310-100mg 现货 100mg ¥866.0 09 Sep. 2021
H11310-20mg 现货 20mg ¥278.0 09 Sep. 2021
H11310-1g 分析对照品,HPLC≥98% 7个工作日 1g ¥3328.0 07 Sep. 2023
H11311-20mg 现货 20mg ¥278.0 09 Sep. 2021
X38015-100mg 现货 100mg ¥406.0 03 Sep. 2021
X38015-250mg 98% 7个工作日 250mg ¥666.0 05 Sep. 2023
Brand:chemscene Supplier:ChemScence
No. Purity Stock Specification Price update time operate
CS-1153-200mg ≥98.0% In-stock 200mg $605.0/ ¥4,394.24 28 Apr. 2022
CS-1153-100mg ≥98.0% In-stock 100mg $352.0/ ¥2,556.65 28 Apr. 2022
CS-1153-50mg ≥98.0% In-stock 50mg $198.0/ ¥1,438.11 28 Apr. 2022
CS-1153-10mg ≥98.0% In-stock 10mg $55.0/ ¥399.48 28 Apr. 2022
Brand:源叶 Supplier:上海源叶生物科技有限公司
No. Purity Stock Specification Price update time operate
B21166-1g 分析标准品,HPLC≥98% 上海:准现货/北京:0/武汉:0/南京:0 1g ¥3500.00 02 Sep. 2021
B21166-100mg 分析标准品,HPLC≥98% 上海:准现货/北京:0/武汉:0/南京:0 100mg ¥600.00 02 Sep. 2021
B21166-20mg 分析标准品,HPLC≥98% 上海:>10/北京:0/武汉:5/南京:2 20mg ¥200.00 02 Sep. 2021
Brand:罗恩试剂 Supplier:上海易恩化学技术有限公司
No. Purity Stock Specification Price update time operate
R049059-25mg 98% 现货 25mg ¥161 11 Sep. 2023
R049059-100mg 98% 现货 100mg ¥403 11 Sep. 2023
R025843-25mg 分析标准试剂 现货 25mg ¥200 11 Sep. 2023
Brand:trc Supplier:TRC
No. Purity Stock Specification Price update time operate
H826000-10mg 0.0 10mg $ 155.00/ ¥1,125.80 07 Sep. 2023
H826000-5mg 0.0 5mg $ 119.00/ ¥864.32 07 Sep. 2023
H826000-2mg 0.0 2mg $91.00/ ¥660.95 18 May. 2023
H826000-1mg 0.0 1mg $ 74.00/ ¥537.48 07 Sep. 2023
Brand:selleck Supplier:Selleck中国
No. Purity Stock Specification Price update time operate
S2251-10mg 98.19% 现货 10mg ¥1302.21 15 Sep. 2023
S2251-5mg 98.19% 现货 5mg ¥892.71 15 Sep. 2023
S2251-2mg 98.19% 现货 2mg ¥647.01 15 Sep. 2023
Brand:bomeibio Supplier:合肥博美生物科技有限责任公司
No. Purity Stock Specification Price update time operate
SH8431-1g ≥98% 现货 1g ¥2200.00元 15 Sep. 2023
SH8431-100mg ≥98% 现货 100mg ¥380.00元 15 Sep. 2023
BZP0394-20mg HPLC≥98% 现货 20mg ¥420元 15 Sep. 2023
Brand:a2bchem Supplier:A2B Chem LLC
No. Purity Stock Specification Price update time operate
AA09688-250mg 98% in stock 250mg $217.00/ ¥1,576.11 05 Jan. 2024
AA09688-100mg 98% in stock 100mg $116.00/ ¥842.53 05 Jan. 2024
AA09688-25mg 98% in stock 25mg $42.00/ ¥305.05 05 Jan. 2024
AA09688-5mg ≥98.0% in stock 5mg $28.00/ ¥203.37 05 Jan. 2024
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