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Salicylic acid | 69-72-7

Product name:Salicylic acid

CAS No:69-72-7
MF:C7H6O3
MW:138.1207
MDL:MFCD00002439
CID:33898
PubChem ID:24899681
Introduction
Salicylic acid (2-hydroxybenzoic acid) inhibits COX-2 activity, and the inhibitory effect is related to the transcription factor (NF- κ B) Activation independent
Names and Identifiers
  • 2-Hydroxybenzoic acid
  • ACIDUM SALICYLICUM
  • ACETYLSALISYLIC ACID IMP C
  • ACETYLSALICYLIC ACID IMPURITY C
  • FEMA 3985
  • SALICYCLIC ACID
  • SALICYLIC ACID
  • RETARDER TSA
  • Sallcylic acid
  • 2-Hydroxybenzoic Acid [for Biochemical Research]
  • Salicylic acid (2-Hydroxybenzoic acid)
  • SALICYLIC ACID(P)
  • SALICYLIC ACID(P) PrintBack
  • SALICYLIC ACID(RG)
  • SALICYLIC ACID(RG) PrintBack
  • Salicylic acid,medicinal
  • Salicylicacid Solution
  • 2-hydroxy-benzoic acid
  • Duoplant
  • Freezone
  • Ionil
  • Keralyt
  • Occlusal
  • o-hydroxybenzoic acid
  • phenol-carboxylic acid
  • Rutranex
  • Salicylic acid, for analysis ACS
  • Saligel
  • Salonil
  • SAX
  • Stri-Dex
  • verrugon
  • Verrugon
  • 水杨酸
  • 武汉水杨酸生产厂家
  • 2-Carboxyphenol
  • o-Carboxyphenol
  • Retarder W
  • Psoriacid-S-stift
  • salicylate
  • Salicylic acid soap
  • Benzoic acid, 2-hydroxy-
  • Salicylic acid collodion
  • Phenol-2-carboxylic acid
  • Trans-Ver-Sal
  • Orthohydroxybenzoic acid
  • 2-Hydroxybenzenecarboxylic acid
  • Acido salicilico
  • Ionil-Plus
  • Salicylic acid, tech.
  • Kyselina salicylova
  • Clear away wart remover
  • Duofil
  • Salicylic Acid
  • Salicylic acid
  • 40%Water soluble salicylic acid
  • o-carboxyphenol
  • o-Hydroxybenzoic acid
  • MLS000069653
  • 2-HYDROXYBENZOIC ACID
  • MLSMR
  • SMR000059163
  • 2-carboxyphenol
  • Salicylic acid,99%
  • MDL:MFCD00002439
  • InChIKey:YGSDEFSMJLZEOE-UHFFFAOYSA-N
  • Inchi:1S/C7H6O3/c8-6-4-2-1-3-5(6)7(9)10/h1-4,8H,(H,9,10)
  • SMILES:O([H])C1=C([H])C([H])=C([H])C([H])=C1C(=O)O[H]
  • BRN:774890
Chemical and Physical Properties

Computed Properties

  • Exact Mass: 138.12g/mol
  • Surface Charge: 0
  • XLogP3: 2.3
  • Hydrogen Bond Donor Count: 2
  • Hydrogen Bond Acceptor Count: 3
  • Rotatable Bond Count: 1
  • Monoisotopic Mass: 138.031694g/mol
  • Monoisotopic Mass: 138.031694g/mol
  • Topological Polar Surface Area: 57.5Ų
  • Heavy Atom Count: 10
  • Complexity: 133
  • Isotope Atom Count: 0
  • Defined Atom Stereocenter Count: 0
  • Undefined Atom Stereocenter Count : 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • Covalently-Bonded Unit Count: 1
  • Tautomer Count: 4
  • Surface Charge: 0

Experimental Properties

  • Odor: SYNTHETIC ACID IS ODORLESS
  • Vapor Density: 4.8 (Air= 1)
  • LogKoa: 7.44 (Octanol-Air partition coefficient)
  • Stability Shelf Life: GRADUALLY DISCOLORS IN SUNLIGHT
  • Autoignition Temperature: 1004 °F (540 °C)
  • Decomposition: When heated to decomp it emits acrid smoke and irritating fumes.
  • Heat of Combustion: 3.026 millijoules/mole
  • Dissociation Constants:pKa1 = 2.98 at 20 °C (carboxylic acid); pKa2 = 13.6 (phenol)
  • Taste: Acrid taste
  • LogP: 1.09040
  • PSA: 57.53000
  • Merck: 8332
  • Refractive Index: 1,565
  • Water Partition Coefficient: 1.8 g/L (20 ºC)
  • FEMA: 3985 | 2-HYDROXYBENZOIC ACID
  • Color/Form: 1.0 mg/mL in acetonitrile
  • Stability/Shelf Life: Stable. Substances to be avoided include oxidizing agents, strong bases, iodine, fluorine. Combustible. Sensitive to light.
  • Solubility: It is slightly soluble in cold water, easily soluble in hot water, ethanol, ether and acetone, and soluble in hot benzene. One gram of this product can be dissolved in 460 ml water, 15 ml hot water, 2.7 ml alcohol, 3 ml acetone, 42 ml chloroform, 3 ml ether, 135 ml benzene, 52 ml turpentine.
  • Sensitiveness: Light Sensitive
  • pka: 2.98(at 25℃)
  • λmax: 210nm, 234nm, 303nm
  • PH: Non0 uorescence (2.5) to dark blue 0 uorescence (4.0)
  • Sublimation Point: 70 ºC
  • Odor: SYNTHETIC ACID IS ODORLESS
Security Information
  • Symbol: GHS05 GHS07
  • RTECS:VO0525000
  • WGK Germany:1
  • Safety Instruction:S26-S39-S37/39
  • Risk Phrases:R22; R36/37/38; R41
  • ป้ายอันตราย: Xn Xn
  • Hazardous Material transportation number:NONH for all modes of transport
  • Hazard Statement:H302,H318
  • Warning Statement:P280,P305+P351+P338
  • Prompt:dangerous
  • Storage Condition:4°C, protect from light
  • Hazard Category Code:22-41
  • Signal Word:Danger
  • TSCA:Yes
  • Toxicity:LD50 i.v. in mice: 500 mg/kg (Sota)
Customs Data
  • HS CODE:2918211000
  • Customs Data:

    China Customs Code:

    2918211000

    Overview:

    2918211000. salicylic acid\Sodium salicylate. VAT:17.0%. Tax refund rate:9.0%. Regulatory conditions:nothing. Minimum tariff:6.5%. general tariff:20.0%

    Declaration elements:

    Product Name, component content, use to

    Summary:

    2918211000. VAT:17.0%. Tax rebate rate:9.0%. . MFN tariff:6.5%. General tariff:20.0%

Synthetic Circuit

Synthetic Circuit 1

Reaction Conditions
1.1 Solvents: Benzene ;  0 °C
2.1 Catalysts: Azobisisobutyronitrile Solvents: Dimethylformamide ;  6 h, reflux
3.1 rt → 500 °C
Reference
Thermal stability and degradation of (4-(acrylamido)-2-hydroxybenzoic acid) homopolymer and copolymer of 4-(acrylamido)-2-hydroxybenzoic acid with methyl methacrylate
Diab, M. A.; et al, Synthesis and Reactivity in Inorganic, 2015, 45(9), 1439-1447

Synthetic Circuit 2

Reaction Conditions
1.1 rt → 500 °C
Reference
Thermal stability and degradation of (4-(acrylamido)-2-hydroxybenzoic acid) homopolymer and copolymer of 4-(acrylamido)-2-hydroxybenzoic acid with methyl methacrylate
Diab, M. A.; et al, Synthesis and Reactivity in Inorganic, 2015, 45(9), 1439-1447
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PB95385-10G 97% 美国:Back order/中国:Back order, >=4 weeks 10g ¥ 2,072.00 05 Apr. 2023
PB95385-5G 97% 美国:Back order/中国:Back order, >=4 weeks 5g ¥ 1,181.00 05 Apr. 2023
PB95385-1G 97% 美国:Back order/中国:Back order, >=4 weeks 1g ¥ 316.00 05 Apr. 2023
Brand:乐研 Supplier:上海皓鸿生物医药科技有限公司
No. Purity Stock Specification Price update time operate
1040220-5kg 98% 上海:6/安徽:7/武汉:5/成都:> 10/天津:/深圳: 5kg ¥œǵƻ 25 Jul. 2023
1040220-1kg 98% 上海:5/安徽:4/武汉:3/成都:> 10/天津:/深圳: 1kg ¥ĸǵǵ 25 Jul. 2023
1040220-500g 98% 上海:7/安徽:> 10/武汉:> 10/成都:5/天津:/深圳: 500g ¥œǖ 25 Jul. 2023
Brand:alfa Supplier:阿法埃莎,赛默飞世尔科技旗下公司
No. Purity Stock Specification Price update time operate
30782-2500g 99+% 2500g ¥3487.00 09 Mar. 2023
30782-500g 99+% 500g ¥890.00 09 Mar. 2023
30782-100g 99+% 100g ¥414.00 09 Mar. 2023
A12253-2500g 99% 2500g ¥1155.00 27 Mar. 2023
A12253-500g 99% 500g ¥315.00 27 Mar. 2023
A12253-250g 99% 250g ¥233.00 27 Mar. 2023
Brand:enaminestore Supplier:Enamine
No. Purity Stock Specification Price update time operate
EN300-16723-100.0g 95% In Stock 100.0g $67.0/ ¥486.63 08 Jul. 2023
EN300-16723-50.0g 95% In Stock 50.0g $50.0/ ¥363.16 08 Jul. 2023
EN300-16723-25.0g 95% In Stock 25.0g $38.0/ ¥276.00 08 Jul. 2023
EN300-16723-10.0g 95% In Stock 10.0g $32.0/ ¥232.42 08 Jul. 2023
EN300-16723-5.0g 95% In Stock 5.0g $29.0/ ¥210.63 08 Jul. 2023
EN300-16723-2.5g 95% In Stock 2.5g $27.0/ ¥196.11 08 Jul. 2023
EN300-16723-1.0g 95% In Stock 1.0g $26.0/ ¥188.84 08 Jul. 2023
EN300-16723-0.5g 95% In Stock 0.5g $21.0/ ¥152.53 08 Jul. 2023
EN300-16723-0.25g 95% In Stock 0.25g $19.0/ ¥138.00 08 Jul. 2023
EN300-16723-0.1g 95% In Stock 0.1g $19.0/ ¥138.00 08 Jul. 2023
EN300-16723-0.05g 95% In Stock 0.05g $19.0/ ¥138.00 08 Jul. 2023
Brand:九鼎 Supplier:上海贤鼎生物科技有限公司
No. Purity Stock Specification Price update time operate
SR533-100g 99% 2.0 100g ¥52.0 30 May. 2022
SR533-500g 99% 500g ¥112.0 30 May. 2022
H1342-25g 99.5%(T) 1~2天 25g ¥505.0 30 May. 2022
H1342-5g 99.5%(T) 1~2天 5g ¥270.0 30 May. 2022
H0206-500g 99.5%(T) 1~2天 500g ¥375.0 30 May. 2022
H0206-25g 99.5%(T) 1~2天 25g ¥145.0 30 May. 2022
Brand:ambeed Supplier:Ambeed
No. Purity Stock Specification Price update time operate
A187633-1kg 98% 中国:-/USA:- 1kg $20.0/ ¥145.26 16 Jun. 2023
A187633-500g 98% 中国:65/USA:8 500g $11.0/ ¥79.90 16 Jun. 2023
A187633-100g 98% 中国:0/USA:8 100g $8.0/ ¥58.11 16 Jun. 2023
A187633-25g 98% 中国:0/USA:12 25g $6.0/ ¥43.58 16 Jun. 2023
A187633-10g 98% 中国:0/USA:6 10g $5.0/ ¥36.32 16 Jun. 2023
Brand:apolloscientific Supplier:Apollo Scientific
No. Purity Stock Specification Price update time operate
OR6245-500g 99% US:1 Pack In Stock/UK:1 Packs in stock. 500g £30.00/ ¥250.03 02 Sep. 2023
OR6245-250g 99% US:1 Pack In Stock/UK:3 Packs in stock. 250g £20.00/ ¥166.68 02 Sep. 2023
OR6245-100g 99% US:In Stock/UK:In Stock 100g £12.00/ ¥100.01 02 Sep. 2023
Brand:labchem Supplier:FUJIFILM
No. Purity Stock Specification Price update time operate
198-14865-500g In stock in Japan 500g JPY 4100/ ¥201.43 15 Sep. 2023
196-14861-100g In stock in Japan 100g JPY 3230/ ¥158.69 15 Sep. 2023
194-14862-25g In stock in Japan 25g JPY 1990/ ¥97.77 15 Sep. 2023
Brand:CityChemical Supplier:City Chemical
No. Purity Stock Specification Price update time operate
S2046-2.5KG ACS,Reagent 2.5kg $156.19/ ¥1,134.44 19 Sep. 2023
S2046-500GM ACS,Reagent 500gm $52.06/ ¥378.12 19 Sep. 2023
S2046-100GM ACS,Reagent 100gm $36.32/ ¥263.80 19 Sep. 2023
S4410-12KG 98% 12kg $261.68/ ¥1,900.63 19 Sep. 2023
S4410-2.5KG 98% 2.5kg $76.86/ ¥558.25 19 Sep. 2023
S4410-500GM 98% 500gm $36.69/ ¥266.49 19 Sep. 2023
Brand:安捷凯 Supplier:武汉安捷凯生物医药科技有限公司
No. Purity Stock Specification Price update time operate
ajci17258-50g 98% 现货 50g ¥730.00 09 Sep. 2023
ajci17258-10g 98% 现货 10g ¥542.00 09 Sep. 2023
Brand:Acmec Supplier:上海吉至生化科技有限公司
No. Purity Stock Specification Price update time operate
S53481-200mg 现货 200mg ¥598.0 07 Sep. 2021
S53481-20mg 20mg ¥98.0 07 Sep. 2021
S53480-500g 500g ¥78.0 07 Sep. 2021
Brand:chemscene Supplier:ChemScence
No. Purity Stock Specification Price update time operate
CS-2007-50g ≥99.0% In-stock 50g $96.0/ ¥697.27 02 Sep. 2021
CS-2007-10g ≥99.0% In-stock 10g $72.0/ ¥522.95 02 Sep. 2021
CS-2007-500mg ≥99.0% In-stock 500mg $50.0/ ¥363.16 02 Sep. 2021
Brand:trc Supplier:TRC
No. Purity Stock Specification Price update time operate
S088125-100g 0.0 100g $523.00/ ¥3,798.65 17 May. 2023
S088125-50g 0.0 50g $413.00/ ¥2,999.70 17 May. 2023
S088125-10g 0.0 10g $ 265.00/ ¥1,924.75 06 Sep. 2023
S088125-1g 0.0 1g $ 167.00/ ¥1,212.95 06 Sep. 2023
S088125-250mg 0.0 250mg $ 108.00/ ¥784.43 06 Sep. 2023
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