Productnaam：Dimethylthiophosphinoyl Chloride

Berekende eigenschappen

• Exacte massa: 127.96200
• Aantal waterstofbonddonors: 0
• Aantal waterstofbondacceptatoren: 1
• Aantal draaibare bindingen: 0
• Monoisotopische massa: 127.9616361g/mol
• Zware atoomtelling: 5
• Complexiteit: 64
• Aantal isotopen atomen: 0
• Gedefinieerd atoomstereocentrumaantal: 0
• Ongedefinieerd atoomstereocentrumaantal: 0
• Gedefinieerd stereocenter aantal obligaties: 0
• Ongedefinieerd stereocenter aantal bindingen: 0
• Aantal covalent gebonden eenheden: 1
• XLogP3: 1.9
• Aantal tautomers: nothing
• Oppervlakte lading: 0
• Topologisch pooloppervlak: 32.1

Experimentele eigenschappen

• LogboekP: 2.52990
• PSA: 41.90000
• Brekindex: 1.538-1.541
• Kookpunt: 78°C/15mmHg(lit.)
• Vlampunt: 105℃
• Kleur/vorm: Colorless or amber liquid with pungent smell
• Oplosbaarheid: Insoluble in water, soluble in ethanol \ benzene \ chloroform \ carbon tetrachloride \ diethyl ether \ ethyl acetate and other organic solvents, slightly soluble in hexane, it will undergo significant isomerization and intermolecular methylation at high temperature, and is prone to hydrolysis \ alcoholysis
• Dichtheid: 1.23

• Symbool: GHS05 GHS07
• Veiligheidsinstructies：8-45-36/37/39-26
• Risicozinnen：R34
• Gevaarlijke goederen ondertekenen： C
• Vervoersnummer gevaarlijk materiaal：UN 1760
• Gevaarverklaring：H290-H302+H312+H332-H314
• Waarschuwingsverklaring：P234-P260-P264-P270-P271-P280-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P390-P405-P406-P501
• Prompt：dangerous
• Opslagvoorwaarde：0-10°C
• PackingGroup：II
• Code gevarencategorie：34-29-20/21/22
• Gevaarklasse：8

• HS-CODE：2930909090
• Douanegegevens：

  China Customs Code:

  2930909090

  Overview:

  2930909090. Other organic sulfur compounds. VAT:17.0%. Tax refund rate:13.0%. Regulatory conditions:nothing. MFN tariff:6.5%. general tariff:30.0%

  Declaration elements:

  Product Name, component content, use to

  Summary:

  2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

• 1. Mechanism of biphosphine disulphide formation in reactions of thiophosphoryl and phosphonothioic halides with Grignard reagents P. C. Crofts,I. S. Fox J. Chem. Soc. B 1968 1416
• 2. Chemical speciation of MeHg+ and Hg2+ in aqueous solution and HEK cells nuclei by means of DNA interacting fluorogenic probes Borja Díaz de Gre?u,José García-Calvo,José Cuevas,Gabriel García-Herbosa,Bego?a García,Natalia Busto,Saturnino Ibeas,Tomás Torroba,Blanca Torroba,Antonio Herrera,Sebastian Pons Chem. Sci. 2015 6 3757
• 3. Syntheses, spectroscopic, and electrochemical properties of dinuclear copper(II) complexes bridged by a single thiolate sulphur atom; X-ray crystal structures of [Cu2(L1)2(SC6H4Cl-4)][PF6] and [Cu2(L2)2(SC6H4CH3-4)][ClO4] Nobuo Aoi,Gen-etsu Matsubayashi,Toshio Tanaka J. Chem. Soc. Dalton Trans. 1987 241
• 4. Studies involving mixed donor macrocyclic ligands. Comparative X-ray diffraction, infrared, and fast atom bombardment mass spectrometric studies of the nickel thiocyanate complexes of three O2N3-donor macrocycles Kenneth R. Adam,Anthony J. Leong,Leonard F. Lindoy,Brian J. McCool,Alfred Ekstrom,Imants Liepa,P. Alexander Harding,Kim Henrick,Mary McPartlin,Peter A. Tasker J. Chem. Soc. Dalton Trans. 1987 2537
• 5. Phosphorus–carbon bond formation in heterobimetallic molybdenum–tungsten alkyne complexes Gillian A. Acum,Martin J. Mays,Paul R. Raithby,Gregory A. Solan J. Chem. Soc. Dalton Trans. 1995 3049
• 6. X-Ray crystal structure characterization of cyclo(hexacyanoborane), (BH2CN)6 Andrew T. McPhail,Dennis L. McFadden J. Chem. Soc. Dalton Trans. 1975 1784
• 7. Dicopper(II) complexes of a macrocyclic ligand containing single hydroxo-, methoxo-, or 1,1-azido-bridges: synthesis, magnetic properties, electron spin resonance spectra, and the crystal and molecular structure of a μ-hydroxo-derivative Michael G. B. Drew,Jane Nelson,Ferida Esho,Vickie McKee,S. Martin Nelson J. Chem. Soc. Dalton Trans. 1982 1837
• 8. Amide bond formation: beyond the myth of coupling reagents Eric Valeur,Mark Bradley Chem. Soc. Rev. 2009 38 606