找化学品上960化工网!
960化工网

3,4-二甲酚 | 95-65-8

3,4-二甲酚
3,4-Xylenol
95-65-8
C8H10O
122.164402484894
24862397
管制类
名称和标识符
MDL MFCD00002304
InChIKey YCOXTKKNXUZSKD-UHFFFAOYSA-N
Inchi 1S/C8H10O/c1-6-3-4-8(9)5-7(6)2/h3-5,9H,1-2H3
SMILES OC1C=C(C)C(C)=CC=1
BRN 1099267
别名信息
- 中文别名 -
  • 3,4-二甲酚
  • 3,4-二甲基苯酚
  • 3,4-二甲苯酚
  • 2,3-二甲基苯酚
  • 3,4-二甲酚标准溶液
  • 3,4-二甲基苯酚,3,4-Dimethylphenol
  • 1,2-二甲基-4-羟基苯
  • 1-羟基-3,4-二甲基苯
  • 4-羟基邻二甲苯
  • 不对称邻二甲苯酚
  • 1-羟基-3,4-二甲苯
  • 1-羟基-3,4-二甲基苯
  • 乙拌磷-D10
  • 3,4-二甲基酚
  • 邻-4-二甲基苯酚
- 英文别名 -
  • 3,4-Dimethylphenol
  • 3,4-Xylenol
  • 4-Dimethylphenol
  • 1-Hydroxy-3,4-dimethylbenzene
  • 3,4-dimethyl-phenol
  • 3,4-DMP
  • 4,5-Dimethylphenol
  • 4-Hydroxy-1,2-dimethylbenzene
  • as-o-xylenol
  • Phenol,3,4-dimethyl
  • 1,2-Dimethyl-4-hydroxybenzene
  • o-Xylenol
  • 1,3,4-Xylenol
  • ai3-01552
  • o-4-Xylenol
  • 3,4-dimethyl-pheno
  • 3 4-XYLENOL 98+%
  • 3,4-DIMETHYLPHENOL PESTANAL
  • 3,4-Dimethylphenol, 98+%
  • 3, 4-Xylenol (3,4-Dimethylphenol)
  • 3,4-Dimethylphenol (ACI)
  • 3,4-Xylenol (8CI)
  • NSC 1549
物化性质
实验特性
LogP 2.00900
PSA 20.23000
Merck 10082
折射率 1.5442
水溶性 微溶
沸点 227 °C(lit.)
熔点 63.0 to 68.0 deg-C
闪点 华氏:230 °F
摄氏:110 °C
FEMA 3596
颜色与性状 白色晶体。
溶解性 难溶于水,能与乙醇、氯仿、乙醚、苯等相混溶。能溶于****水溶液。
敏感性 对光敏感
密度 1,138 g/cm3
计算特性
精确分子量 122.07300
氢键供体数量 1
氢键受体数量 1
可旋转化学键数量 0
同位素质量 122.073
重原子数量 9
复杂度 90.6
同位素原子数量 0
确定原子立构中心数量 0
不确定原子立构中心数量 0
确定化学键立构中心数量 0
不确定化学键立构中心数量 0
共价键单元数量 1
疏水参数计算参考值(XlogP)
互变异构体数量 9
表面电荷 0
拓扑分子极性表面积 20.2A^2
国际标准相关数据
EINECS 202-439-5
海关数据
海关编码 2907299090
海关数据

中国海关编码:

2907199090

概述:

2907199090 其他一元酚. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%

申报要素:

品名, 成分含量, 用途

Summary:

2907199090 other monophenols VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

合成路线

合成路线:1 步

反应条件:
参考文献:
Reaction of Resorcinol with α,β-Unsaturated Ketones
Livant, P.; Xu, Weizheng, Journal of Organic Chemistry, 1998, 63(3), 636-641

合成路线:1 步

反应条件:
参考文献:
Process for the preparation of phenols from aryldiazonium salts in mixture of solvents
, European Patent Organization, , ,

合成路线:1 步

反应条件:
参考文献:
Base-promoted, mild and highly efficient conversion of arylboronic acids into phenols with tert-butyl hydroperoxide
Guo, Shengmei; Lu, Lin; Cai, Hu, Synlett, 2013, 24(13), 1712-1714

合成路线:1 步

反应条件:
参考文献:
Au-Pd alloy nanoparticles supported on layered double hydroxide for heterogeneously catalyzed aerobic oxidative dehydrogenation of cyclohexanols and cyclohexanones to phenols
Jin, Xiongjie; Taniguchi, Kento; Yamaguchi, Kazuya; Mizuno, Noritaka, Chemical Science, 2016, 7(8), 5371-5383

合成路线:1 步

反应条件:
参考文献:
Ecofriendly solvent free microwave induced organic rearrangements of alkyl phenyl ethers in dry media conditions
Easwaramurthy, M.; Selvakumar, S.; Raju, G. J., Organic Chemistry: An Indian Journal, 2006, 2(5-6), 127-130

合成路线:1 步

反应条件:
参考文献:
CuI-nanoparticles-catalyzed selective synthesis of phenols, anilines, and thiophenols from aryl halides in aqueous solution
Xu, Hua-Jian; Liang, Yu-Feng; Cai, Zhen-Ya; Qi, Hong-Xia; Yang, Chun-Yan; et al, Journal of Organic Chemistry, 2011, 76(7), 2296-2300

合成路线:1 步

反应条件:
参考文献:
AlCl3.6H2O/KI/CH3CN/H2O. An efficient and versatile system for chemoselective C-O bond cleavage and formation of halides and carbonyl compounds from alcohols in hydrated media
Gogoi, Pranjal; Konwar, Dilip; Das Sharma, Saikat; Gogoi, Prodip Kumar, Synthetic Communications, 2006, 36(9), 1259-1264

合成路线:1 步

反应条件:
参考文献:
Microwave-assisted copper-catalyzed hydroxylation of aryl halides in water
Ke, Fang; Chen, Xiaole; Li, Zhengkai; Xiang, Haifeng; Zhou, Xiangge, RSC Advances, 2013, 3(45), 22837-22840

合成路线:1 步

反应条件:
参考文献:
Polymer-supported eosin Y as a reusable photocatalyst for visible light mediated organic transformations
Sridhar, Arunasalam; Rangasamy, Rajmohan; Selvaraj, Mari, New Journal of Chemistry, 2019, 43(46), 17974-17979

合成路线:1 步

反应条件:
参考文献:
Insight into the solvent, temperature and time effects on the hydrogenolysis of hydrolyzed lignin
Shu, Riyang; Zhang, Qi; Ma, Longlong; Xu, Ying; Chen, Pengru; et al, Bioresource Technology, 2016, 221, 568-575

合成路线:1 步

反应条件:
参考文献:
Catalytic hydrotreatment of pyrolytic lignins from different sources to biobased chemicals: Identification of feed-product relations
Figueiredo, M. B.; Deuss, P. J.; Venderbosch, R. H.; Heeres, H. J., Biomass and Bioenergy, 2020, 134,

合成路线:1 步

反应条件:
参考文献:
Simple and Regioselective Reductive Cleavage of Tetrahydropyranyl Ethers to Alcohols
Srikrishna, A.; Sattigeri, J. A.; Viswajanani, R.; Yelamaggad, C. V., Journal of Organic Chemistry, 1995, 60(7),

合成路线:1 步

反应条件:
参考文献:
Examining the vinyl moiety as a protecting group for hydroxyl (-OH) functionality under basic conditions
Voronin, Vladimir V.; Ledovskaya, Maria S.; Rodygin, Konstantin S.; Ananikov, Valentine P., Organic Chemistry Frontiers, 2020, 7(11), 1334-1342

合成路线:1 步

反应条件:
参考文献:
Electrochemical-induced hydroxylation of aryl halides in the presence of Et3N in water
Yang, Li; Zhuang, Qinglong; Wu, Mei; Long, Hua; Lin, Chen; et al, Organic & Biomolecular Chemistry, 2021, 19(29), 6417-6421

合成路线:1 步

反应条件:
参考文献:
Microwave-assisted selective cleavage of sulfonates and sulfonamides in dry media
Sabitha, Gowravaram; Abraham, Sunny; Reddy, B. V. Subba; Yadav, J. S., Synlett, 1999, (11), 1745-1746

合成路线:1 步

反应条件:
参考文献:
Highly efficient and selective deprotection method for prenyl, geranyl, and phytyl ethers and esters using boron trifluoride-etherate
Narender, T.; Venkateswarlu, K.; Madhur, G.; Reddy, K. Papi, Synthetic Communications, 2013, 43(1), 26-33

合成路线:1 步

反应条件:
参考文献:
A Ni-Mg-Al layered triple hydroxide-supported Pd catalyst for heterogeneous acceptorless dehydrogenative aromatization
Jin, Xiongjie; Taniguchi, Kento; Yamaguchi, Kazuya; Nozaki, Kyoko; Mizuno, Noritaka, Chemical Communications (Cambridge, 2017, 53(38), 5267-5270

合成路线:1 步

反应条件:
参考文献:
Preparation, characterization and use of 1,3-disulfonic acid imidazolium hydrogen sulfate as an efficient, halogen-free and reusable ionic liquid catalyst for the trimethylsilyl protection of hydroxyl groups and deprotection of the obtained trimethylsilanes
Shirini, Farhad; Khaligh, Nader Ghaffari; Akbari-Dadamahaleh, Somayeh, Journal of Molecular Catalysis A: Chemical, 2012, 365, 15-23

合成路线:1 步

反应条件:
参考文献:
Copper-catalyzed hydroxylation of aryl halides with tetrabutylammonium hydroxide: synthesis of substituted phenols and alkyl aryl ethers
Paul, Rajesh; Ali, Ashif Md; Punniyamurthy, Tharmalingam, Synthesis, 2010, (24), 4268-4272

合成路线:1 步

反应条件:
参考文献:
Photocatalytic one-pot method for synthesizing phenol or derivative thereof in water phase
, China, , ,

合成路线:1 步

反应条件:
参考文献:
Visible-light promoted hydroxylation of aryl halides under mild reaction conditions in neat water
Xu, Xiuzhi; Zhang, Fan; Huang, Sheng; Zhang, Zhiqiang; Ke, Fang, Youji Huaxue, 2020, 40(9), 2912-2918

合成路线:1 步

反应条件:
参考文献:
Transition-metal-free Baeyer-Villiger oxidation of benzaldehydes to phenols using Na2S2O8
Li, Wei; Chen, Lin-Lin; Han, Ke; Liu, Zhi-Bin; Luan, You-Shun; et al, Journal of Chemical Research, 2019, 43(3-4), 115-118
相关文献
专业数据库参考
PubChemId 24862397
参考资料
Reaxys RN 1099267
Beilstein 6,480
产品用途
用于制改性聚酰亚胺、杀虫剂、染料等
管制类化学品!
1. 本品属于管制类化学品,任何个人不得购买。
2. 购买本品,贵司需具有相应产品有效期内的采购或者使用资质(如《危险化学品经营许可证》或《危险化学品使用许可证》)。
3. 本品的物流、仓储均需为具有相应资质的物流公司和仓储公司。严禁使用快递运送化学品,装卸、运输、仓储流程应按照相关法律法规的要求严格控制。
4. 本品仅作产品展示,不作交易使用,详情请参照 《危险化学品安全管理条例》《易制毒化学品管理条例》或化学品相关法规。
5. 只有提供相应产品有效期内的《危险化学品安全生产许可证》或《危险化学品经营许可证》的企业才可以在本站展示商品信息,其他管制类商品(如易制爆危险化学品、易制毒化学品、剧毒化学品),暂不可在本站展示信息。
960化工网为您提供3,4-二甲酚专业化合物百科信息,包括中文名,英文名,分子式,分子量,以及该化合物的CasNo.:95-65-8,和相关理化性质;并提供了优质生产厂家信息包括厂家名称和联系方式等;| WAP 版:95-65-8
平台客服
平台客服

平台在线客服