找化学品上960化工网!
960化工网

N-乙基邻甲苯胺 | 94-68-8

N-乙基邻甲苯胺
N-Ethyl-o-toluidine
94-68-8
C9H13N
135.206222295761
如需查看该化合物的详细结构式,mol文件,smile,InChi 请点击:N-乙基邻甲苯胺结构式
7201
N-乙基邻甲苯胺价格
名称和标识符
MDL MFCD00026695
InChIKey MWOUGPLLVVEUMM-UHFFFAOYSA-N
Inchi 1S/C9H13N/c1-3-10-9-7-5-4-6-8(9)2/h4-7,10H,3H2,1-2H3
SMILES C1C=C(NCC)C(C)=CC=1
BRN 2689722
别名信息
- 中文别名 -
  • N-乙基邻甲苯胺
  • N-乙基-邻甲苯胺
  • N-乙基-2-甲基苯胺
  • N-Ethyl-o-toluidine N-乙基邻甲苯胺
  • N-乙基甲苯胺
  • N-乙基邻***胺
  • N-乙基邻甲苯胺,AR
  • N-乙基邻甲苯胺,CP
  • 2-(乙氨基)甲苯
  • 乙氨基邻甲苯
  • N-乙基邻苄胺
- 英文别名 -
  • N-Ethyl-2-methylaniline
  • 2-Ethylaminotoluene
  • N-Ethyl-o-toluidine
  • C9H13N
  • N-​Ethyl-​o-​toluidine (N-Ethyl-2-methyl-benzenamine)
  • 2-(Ethylamino)toluene
  • N-Ethyl-2-aminotoluene
  • N-Ethyl-2-methylbenzenamine (ACI)
  • o-Toluidine, N-ethyl- (7CI, 8CI)
  • 1-(Ethylamino)-2-methylbenzene
  • 2-Methyl-N-ethylaniline
  • N-Ethyl-N-(o-tolyl)amine
  • N-Ethyl-o-methylaniline
  • NSC 8888
  • o-Methyl-N-ethylaniline
物化性质
实验特性
LogP 2.49980
PSA 12.03000
折射率 n20/D 1.547(lit.)
水溶性 不溶
沸点 214°C(lit.)
熔点 -6.87°C (estimate)
闪点 华氏:192.2 °F
摄氏:89 °C
FEMA 2909
溶解度 1g/l
颜色与性状 无色透明液体
溶解性 易溶于乙醇和乙醚。
敏感性 对空气敏感
密度 0.938 g/mL at 25 °C(lit.)
计算特性
精确分子量 135.10500
氢键供体数量 1
氢键受体数量 1
可旋转化学键数量 2
同位素质量 135.105
重原子数量 10
复杂度 90.7
同位素原子数量 0
确定原子立构中心数量 0
不确定原子立构中心数量 0
确定化学键立构中心数量 0
不确定化学键立构中心数量 0
共价键单元数量 1
疏水参数计算参考值(XlogP)
互变异构体数量
表面电荷 0
拓扑分子极性表面积 12A^2
国际标准相关数据
EINECS 202-354-3
海关数据
海关编码 2921499090
海关数据

中国海关编码:

2921499090

概述:

2921499090 其他芳香单胺及衍生物及它们的盐. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%

申报要素:

品名, 成分含量, 用途

Summary:

2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

合成路线

合成路线:1 步

反应条件:
参考文献:
Preparation of aromatic secondary amines from nitro compounds and nitriles
, Japan, , ,

合成路线:1 步

反应条件:
参考文献:
Boron Lewis Acid Promoted Ruthenium-Catalyzed Hydrogenation of Amides: An Efficient Approach to Secondary Amines
Yuan, Ming-Lei; Xie, Jian-Hua; Zhou, Qi-Lin, ChemCatChem, 2016, 8(19), 3036-3040

合成路线:1 步

反应条件:
参考文献:
Preparation of 3-ethylamino-p-methylphenol
, China, , ,

合成路线:1 步

反应条件:
参考文献:
Tailored Cobalt-Catalysts for Reductive Alkylation of Anilines with Carboxylic Acids under Mild Conditions
Liu, Weiping; Sahoo, Basudev; Spannenberg, Anke; Junge, Kathrin; Beller, Matthias, Angewandte Chemie, 2018, 57(36), 11673-11677

合成路线:1 步

反应条件:
参考文献:
Facile N-alkylation of anilines with alcohols over Raney nickel under microwave irradiation
Jiang, Yu-Lin; Hu, Yu-Qiao; Feng, Shu-Qing; Wu, Ji-Shan; Wu, Zu-Wang; et al, Synthetic Communications, 1996, 26(1), 161-4

合成路线:1 步

反应条件:
参考文献:
Acylspiro[azetidine-cyclobutane] compounds for inhibiting monoacylglycerol lipase (MAGL) and their preparation
, World Intellectual Property Organization, , ,

合成路线:1 步

反应条件:
参考文献:
Hydrogenation and N-alkylation of anilines and imines via transfer hydrogenation with homogeneous nickel compounds
Benitez-Medina, G. Eliad; Garcia, Juventino J., Dalton Transactions, 2019, 48(47), 17579-17587

合成路线:1 步

反应条件:
参考文献:
Reductive monoalkylation of aromatic and aliphatic nitro compounds and the corresponding amines with nitriles
Nacario, Ruel; Kotakonda, Shailaja; Fouchard, David M. D.; Tillekeratne, L. M. Viranga; Hudson, Richard A., Organic Letters, 2005, 7(3), 471-474

合成路线:1 步

反应条件:
参考文献:
Chelating Bis(1,2,3-triazol-5-ylidene) Rhodium Complexes: Versatile Catalysts for Hydrosilylation Reactions
Nguyen, Thanh V. Q.; Yoo, Woo-Jin; Kobayashi, Shu, Advanced Synthesis & Catalysis, 2016, 358(3), 452-458

合成路线:1 步

反应条件:
参考文献:
Selective N-alkylation of amines using nitriles under hydrogenation conditions: facile synthesis of secondary and tertiary amines
Ikawa, Takashi; Fujita, Yuki; Mizusaki, Tomoteru; Betsuin, Sae; Takamatsu, Haruki; et al, Organic & Biomolecular Chemistry, 2012, 10(2), 293-304

合成路线:1 步

反应条件:
参考文献:
Factors affecting the selectivity of the photocatalytic conversion of nitroaromatic compounds over TiO2 to valuable nitrogen-containing organic compounds
Hakki, Amer; Dillert, Ralf; Bahnemann, Detlef W., Physical Chemistry Chemical Physics, 2013, 15(8), 2992-3002

合成路线:1 步

反应条件:
参考文献:
Alkylation of Aromatic Amines with Trialkyl Amines Catalyzed by a Defined Iridium Complex with a 2-Hydroxypyridylmethylene Fragment
Deng, Danfeng; Hu, Bowen ; Zhang, Ziyu; Mo, Shengkai; Yang, Min ; et al, Organometallics, 2019, 38(9), 2218-2226

合成路线:1 步

反应条件:
参考文献:
Selective Pd-Catalyzed Monoarylation of Small Primary Alkyl Amines through Backbone-Modification in Ylide-Functionalized Phosphines (YPhos)
Rodstein, Ilja; Prendes, Daniel Sowa; Wickert, Leon; Paassen, Maurice; Gessner, Viktoria H., Journal of Organic Chemistry, 2020, 85(22), 14674-14683

合成路线:1 步

反应条件:
参考文献:
Mild reductive rearrangement of oximes and oxime ethers to secondary amines with hydrosilanes catalyzed by B(C6F5)3
Fang, Huaquan; Wang, Guoqiang; Oestreich, Martin, Organic Chemistry Frontiers, 2021, 8(13), 3280-3285

合成路线:1 步

反应条件:
参考文献:
On the asymmetric iridium-catalyzed N-allylation of amino acid esters: Improved selectivities through structural variation of the chiral phosphoramidite ligand
Albat, Dominik; Kocher, Alicia; Witt, Julia; Schmalz, Hans-Guenther, European Journal of Organic Chemistry, 2022, 2022(12),

合成路线:1 步

反应条件:
参考文献:
Bulk-scale preparation of ethyl 2-[3,6-bis(N-ethylamino)-2,7-dimethyl-3-hydroxanth-9-yl]benzoate hydrochloride
, China, , ,

合成路线:1 步

反应条件:
参考文献:
Nickel-Catalyzed Amination of Aryl Chlorides with Ammonia or Ammonium Salts
Green, Rebecca A.; Hartwig, John F., Angewandte Chemie, 2015, 54(12), 3768-3772

合成路线:1 步

反应条件:
参考文献:
N-Ethylpiperidine
Wollensak, J.; Closson, R. D., Organic Syntheses, 1963, 43, 45-8

合成路线:1 步

反应条件:
参考文献:
Selective monoalkylation of amines
Dalla Croce, Piero; La Rosa, Concetta; Ritieni, Alberto, Journal of Chemical Research, 1988, (10), 346-7

合成路线:1 步

反应条件:
参考文献:
A facile, one-pot reductive alkylation of aromatic and heteroaromatic amines in aqueous micellar media: a chemoenzymatic approach
Ganesh, Krithika; Sambasivam, Ganesh; S, Karthikeyan, Organic & Biomolecular Chemistry, 2023, 21(20), 4264-4268
相关文献
专业数据库参考
PubChemId 7201
参考资料
Reaxys RN 2689722
Beilstein 12(3)1843
产品用途
用于染料、医药及其他有机合成
960化工网为您提供N-乙基邻甲苯胺专业化合物百科信息,包括中文名,英文名,分子式,分子量,以及该化合物的CasNo.:94-68-8,和相关理化性质;并提供了优质生产厂家信息包括厂家名称和联系方式等;| WAP 版:94-68-8
平台客服 平台客服

平台在线客服