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β-萘甲醚 | 93-04-9

β-萘甲醚
2-Methoxynaphthalene
93-04-9
C11H10O
158.196503162384
如需查看该化合物的详细结构式,mol文件,smile,InChi 请点击:β-萘甲醚结构式
24848894
β-萘甲醚价格
名称和标识符
MDL MFCD00004061
InChIKey LUZDYPLAQQGJEA-UHFFFAOYSA-N
Inchi 1S/C11H10O/c1-12-11-7-6-9-4-2-3-5-10(9)8-11/h2-8H,1H3
SMILES O(C)C1C=C2C(C=CC=C2)=CC=1
BRN 1859408
别名信息
- 中文别名 -
  • β-萘甲醚
  • 2-甲氧基萘
  • 2-萘甲醚
  • 乙位萘甲醚
  • α-萘甲醚
  • 2-Methoxynaphthalene 2-甲氧基萘
  • 2-甲氧基萘(2-萘甲醚)
  • 2-甲氧萘
  • β-萘基甲基醚
  • 甲基-β-萘基醚
  • 乙位萘甲醚 / 2-萘甲醚
- 英文别名 -
  • 2-Methoxynaphthalene
  • Methyl 2-naphthyl ether
  • yara-yara
  • 2-methoxy-naphthalene
  • 2-Naphthol methyl ether
  • 2-Naphthyl methyl ether
  • 6-methoxynaphthalene
  • Naphthalene,2-methoxy
  • Nerolin
  • Yara yara
  • Yura yara
  • β-Naphthyl methyl ether
  • Naproxen Impurity M
  • beta-Naphthyl methyl ether
  • (1R,4R,5S,7S,8R,9S,12R,13R,21E,30R,33S,34R,37R,38S,40S,41R,42S,45R,46R,54E,63R,66S,67R,70R,71S,73S,7
  • (1R,4R,5S,7S,8R,9S,12R,13R,21E,30R,33S,34R,37R,38S,40S,41R,42S,45R,46R,54E,63R,66S,67R,70R,71S,73S,7
  • 2-Methoxynaphthalene (ACI)
  • Ether, methyl 2-naphthyl (3CI)
  • 6-Methoxy-2-naphthalene
  • Methyl β-naphthyl ether
  • Nerolin (old)
  • Nerolin yara yara
  • NSC 4171
  • β-Methoxynaphthalene
  • β-Naphthol methyl ether
  • 2-Methoxynaphthalene
  • 2-Methoxynaphthalene (Nerolin)
  • Neroline Yara Yara
物化性质
实验特性
LogP 2.84840
PSA 9.23000
Merck 5997
折射率 1.5440 (estimate)
水溶性 不溶
沸点 274 °C(lit.)
熔点 70-73 °C (lit.)
闪点 华氏:208.4 °F
摄氏:98 °C
FEMA 4704 | BETA-NAPHTHYL METHYL ETHER
溶解度 H2O: soluble (completely)
颜色与性状 无色片状结晶
稳定性 Stable. Combustible. Incompatible with strong oxidizing agents.
溶解性 不溶于水,溶于乙醚、苯和氯仿,稍溶于二硫化碳,微溶于甲醇和乙醇。能随水蒸气一同挥发。
密度 1.064 g/mL at 25 °C(lit.)
计算特性
精确分子量 158.07300
氢键供体数量 9
氢键受体数量 18
可旋转化学键数量 0
同位素质量 158.073165
重原子数量 126
复杂度 3630
同位素原子数量 0
确定原子立构中心数量 0
不确定原子立构中心数量 0
确定化学键立构中心数量 0
不确定化学键立构中心数量 0
共价键单元数量 1
疏水参数计算参考值(XlogP) 17.3
表面电荷 0
拓扑分子极性表面积 351
海关数据
海关编码 29093090
海关数据

中国海关编码:

2909309090

概述:

2909309090 其他芳香醚及其卤化衍生物、磺化、硝化衍生物(包括亚硝化衍生物)。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

申报要素:

品名, 成分含量, 用途

Summary:

2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

合成路线

合成路线:1 步

反应条件:
参考文献:
Preparation of a cost-effective Ni-Ag bimetallic catalyst for hydrodehalogenation of aryl halides under mild conditions
Deng, Jiazhu; Xue, Teng; Wu, Haihong; Wu, Peng, New Journal of Chemistry, 2022, 46(25), 12169-12176

合成路线:1 步

反应条件:
参考文献:
Synthesis of 6-propyl-2-naphthol
Li, Yan-yan; Liu, Qian-feng, Yingyong Huagong, 2014, 43(5), 901-904

合成路线:1 步

反应条件:
参考文献:
Rhodium-catalyzed carbon-cyano bond cleavage reactions using organosilicon reagents
Kita, Yusuke; Tobisu, Mamoru; Chatani, Naoto, Yuki Gosei Kagaku Kyokaishi, 2010, 68(11), 1112-1122

合成路线:1 步

反应条件:
参考文献:
A mixed naphthyl-phenyl phosphine ligand motif for Suzuki, Heck, and hydrodehalogenation reactions
Demchuk, Oleg M.; Yoruk, Bilge; Blackburn, Tom; Snieckus, Victor, Synlett, 2006, (18), 2908-2913

合成路线:1 步

反应条件:
参考文献:
C-H Nickelation of Naphthyl Phosphinites: Electronic and Steric Limitations, Regioselectivity, and Tandem C-P Functionalization
Mangin, Loic P.; Zargarian, Davit, Organometallics, 2019, 38(24), 4687-4700

合成路线:1 步

反应条件:
参考文献:
Rhodium-catalyzed reductive decyanation of nitriles using hydrosilane as a reducing agent: scope, mechanism and synthetic application
Tobisu, Mamoru; Nakamura, Ryo; Kita, Yusuke; Chatani, Naoto, Bulletin of the Korean Chemical Society, 2010, 31(3), 582-587

合成路线:1 步

反应条件:
参考文献:
Method for synthesizing aryl methyl ether
, China, , ,

合成路线:1 步

反应条件:
参考文献:
Catalytic O-methylation of phenols with dimethyl carbonate to aryl methyl ethers using [BMIm]Cl
Shen, Zhen Lu; Jiang, Xuan Zhen; Mo, Wei Min; Hu, Bao Xiang; Sun, Nan, Green Chemistry, 2005, 7(2), 97-99

合成路线:1 步

反应条件:
参考文献:
Selective Reductive Removal of Ester and Amide Groups from Arenes and Heteroarenes through Nickel-Catalyzed C-O and C-N Bond Activation
Yue, Huifeng; Guo, Lin; Lee, Shao-Chi; Liu, Xiangqian; Rueping, Magnus, Angewandte Chemie, 2017, 56(14), 3972-3976

合成路线:1 步

反应条件:
参考文献:
Highly active, well-defined (cyclopentadiene)(N-heterocyclic carbene)palladium chloride complexes for room-temperature Suzuki-Miyaura and Buchwald-Hartwig cross-coupling reactions of aryl chlorides and deboronation homocoupling of arylboronic acids
Jin, Zhong; Guo, Su-Xian; Gu, Xiao-Peng; Qiu, Ling-Ling; Song, Hai-Bing; et al, Advanced Synthesis & Catalysis, 2009, 351(10), 1575-1585

合成路线:1 步

反应条件:
参考文献:
Transforming Non-innocent Phenalenyl to a Potent Photoreductant: Captivating Reductive Functionalization of Aryl Halides through Visible-Light-Induced Electron Transfer Processes
Pathania, Vishali ; Roy, Vishal Jyoti; Roy, Sudipta Raha, Journal of Organic Chemistry, 2022, 87(24), 16550-16566

合成路线:1 步

反应条件:
参考文献:
Aqueous reaction solvent containing carboxybetains used for organic chemistry
, Japan, , ,

合成路线:1 步

反应条件:
参考文献:
Methylation of phenol and its derivatives with dimethyl carbonate in the presence of Mn2(CO)10, W(CO)6, and Co2(CO)8
Khusnutdinov, R. I.; Shchadneva, N. A.; Mayakova, Yu. Yu., Russian Journal of Organic Chemistry, 2015, 51(3), 330-334

合成路线:1 步

反应条件:
参考文献:
Process for continuously preparing β-naphthyl methyl ether
, China, , ,

合成路线:1 步

反应条件:
参考文献:
Practical heterogeneous photoredox/nickel dual catalysis for C-N and C-O coupling reactions
Liu, Yi-Yin; Liang, Dong; Lu, Liang-Qiu; Xiao, Wen-Jing, Chemical Communications (Cambridge, 2019, 55(33), 4853-4856

合成路线:1 步

反应条件:
参考文献:
Palladium(0)-catalyzed electroreductive carboxylation of aryl halides, β-bromostyrene, and allyl acetates with carbon dioxide
Torii, Sigeru; Tanaka, Hideo; Hamatani, Takeshi; Morisaki, Kazuo; Jutand, Anny; et al, Chemistry Letters, 1986, (2), 169-72

合成路线:1 步

反应条件:
参考文献:
Preparation of DL-naproxen
, China, , ,

合成路线:1 步

反应条件:
参考文献:
Methylation with Dimethyl Carbonate/Dimethyl Sulfide Mixtures: An Integrated Process without Addition of Acid/Base and Formation of Residual Salts
Lui, Yuen Wai; Chan, Bun ; Lui, Matthew Y., ChemSusChem, 2022, 15(3),

合成路线:1 步

反应条件:
参考文献:
Etherification of phenols catalyzed by solid-liquid phase transfer catalyst PEG-400 without solvent
Cao, Yu-Qing; Pei, Ben-Gao, Synthetic Communications, 2000, 30(10), 1759-1766

合成路线:1 步

反应条件:
参考文献:
Catalytic Reductions Without External Hydrogen Gas: Broad Scope Hydrogenations with Tetrahydroxydiboron and a Tertiary Amine
Korvinson, Kirill A.; Akula, Hari K.; Malinchak, Casina T.; Sebastian, Dellamol; Wei, Wei; et al, Advanced Synthesis & Catalysis, 2020, 362(1), 166-176

合成路线:1 步

反应条件:
参考文献:
Synthesis of β-naphthyl methyl ether catalyzed by activated carbon modified by H2SO4 under ultrasonic irradiation
Xiao, Dongcai; Yang, Jinhui, Jingxi Huagong, 2010, 27(10), 1038-1040
相关文献
专业数据库参考
PubChemId 24848894
参考资料
Reaxys RN 1859408
Beilstein 1859408
产品用途
主要用于调配皂用香精、大众化的花露水和古龙香水
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