找化学品上960化工网!
960化工网

4,4'-二羟基联苯 | 92-88-6

4,4'-二羟基联苯
4,4'-Dihydroxybiphenyl
92-88-6
C12H10O2
186.206603527069
如需查看该化合物的详细结构式,mol文件,smile,InChi 请点击:4,4'-二羟基联苯结构式
24863103
4,4'-二羟基联苯价格
名称和标识符
MDL MFCD00002348
InChIKey VCCBEIPGXKNHFW-UHFFFAOYSA-N
Inchi 1S/C12H10O2/c13-11-5-1-9(2-6-11)10-3-7-12(14)8-4-10/h1-8,13-14H
SMILES OC1C=CC(C2C=CC(O)=CC=2)=CC=1
BRN 1908886
别名信息
- 中文别名 -
  • 4,4'-二羟基联苯
  • 4,4'-联苯二酚
  • 防老剂DOD
  • 4,4'-联苯酚
  • 4,4 -二羟基联苯
  • 4,4\'-二羟基联苯
  • 4,4’-二羟基联苯
  • 4,4’-联苯二酚
  • 4,4′-二羟基联苯
  • 4,4'-Biphenol 4,4'-联苯酚
  • 4,4''-二羟基联苯
  • 4,4'-二羟基联苯(联苯二酚)
  • 4,4鈥?-Biphenol
  • 4,4-联苯二酚
  • 4.4-二羟基联苯
  • 联苯二酚
  • (1,1'-联苯基)-4,4'-二醇
  • 4,4‘-二羟基联苯
  • 4,4’-二羟基联苯 标准品
  • 4,4'-二苯酚
  • 4,4'-二羟基联苯(DOD)
  • 4,4'-联苯二醇
  • 医药中间体
  • 4,4′-二苯酚
  • 4,4′-联苯二酚
  • 4,4′-联苯酚
  • 防老剂 DOD
- 英文别名 -
  • 4,4'-Dihydroxybiphenyl
  • 4,4-Dihydroxybiphenyl
  • PPDP
  • p,p-Biphenol
  • Biphenyl-4,4-diol
  • p,p-Diphenol
  • 4,4-Biphenyldiol
  • 4,4-Dihydroxy Diphenyl
  • 4,4'-Dihydroxydiphenyl (DOD)
  • 4-(4-hydroxyphenyl)phenol
  • 4,4'-BIPHENOL
  • 4,4-Biphenol
  • 4,4'-Biphenyldiol
  • 4,4′-Dihydroxybiphenyl
  • 4,4`-Dihydroxybiphenyl
  • 4,4'-bis-hydroxybiphenyl
  • 4,4'-Dihydroxydiphenyl
  • 4,4'-Dioxydiphenyl
  • 4,4'-Diphenol
  • Antioxidant DOD
  • Biphenyl-4,4'-diol
  • p,p'-Biphenol
  • p,p'-Diphenol
  • 4,4′-Biphenyldiol (8CI)
  • 4,4′-Biphenol
  • 4,4′-Bisphenol
  • 4,4′-Dihydroxy-1,1′-biphenyl
  • 4,4′-Dihydroxydiphenyl
  • 4,4′-Diphenol
  • 4-(4-Hydroxyphenyl)phenol
  • ASM DOD
  • B 0464
  • BPL
  • BPL (phenol)
  • DOD
  • NSC 8711
  • p,p′-Biphenol
  • p,p′-Dihydroxybiphenyl
  • p,p′-Diphenol
  • p-Dihydroxydiphenyl
  • p-Diphenol
  • 4,4'-Biphenol
物化性质
实验特性
LogP 2.76480
PSA 40.46000
折射率 1.6010 (estimate)
水溶性 略溶
沸点 280.69°C (rough estimate)
熔点 280-282 °C (lit.)
闪点 176.1 °C
颜色与性状 Powder
溶解性 溶于乙醇和乙醚,微溶于水和苯。
敏感性 对光敏感
密度 1.22
计算特性
精确分子量 186.06800
氢键供体数量 2
氢键受体数量 2
可旋转化学键数量 1
同位素质量 186.068
重原子数量 14
复杂度 145
同位素原子数量 0
确定原子立构中心数量 0
不确定原子立构中心数量 0
确定化学键立构中心数量 0
不确定化学键立构中心数量 0
共价键单元数量 1
疏水参数计算参考值(XlogP)
互变异构体数量 5
表面电荷 0
拓扑分子极性表面积 40.5A^2
国际标准相关数据
EINECS 202-200-5
海关数据
海关编码 29061900
海关数据

中国海关编码:

2907299090

概述:

2907299090 其他多元酚,酚醇。监管条件:AB(入境货物通关单,出境货物通关单)。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

申报要素:

品名, 成分含量, 用途

监管条件:

A.入境货物通关单
B.出境货物通关单

检验检疫类别:

R.进口食品卫生监督检验
S.出口食品卫生监督检验
M.进口商品检验
N.出口商品检验

Summary:

2907299090 polyphenols; phenol-alcohols。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:5.5%。general tariff:30.0%

生产方法和用途
用途 用作橡胶和乳胶的防老剂,可用于浅色橡胶制品、食品包装用胶和医用乳胶制品
合成路线

合成路线:1 步

反应条件:
参考文献:
Preparation of 4,4'-biphenols as materials for heat-resistant engineering plastics
, Japan, , ,

合成路线:1 步

反应条件:
参考文献:
Preparation, characterization and use of 1,3-disulfonic acid imidazolium hydrogen sulfate as an efficient, halogen-free and reusable ionic liquid catalyst for the trimethylsilyl protection of hydroxyl groups and deprotection of the obtained trimethylsilanes
Shirini, Farhad; Khaligh, Nader Ghaffari; Akbari-Dadamahaleh, Somayeh, Journal of Molecular Catalysis A: Chemical, 2012, 365, 15-23

合成路线:1 步

反应条件:
参考文献:
Catalysis by solid superacids. 21. Nafion-H catalyzed de-tert-butylation of aromatic compounds
Olah, George A.; Prakash, G. K. Surya; Iyer, Pradeep S.; Tashiro, Masashi; Yamato, Takehiko, Journal of Organic Chemistry, 1987, 52(9), 1881-4

合成路线:1 步

反应条件:
参考文献:
Suzuki-Miyaura Coupling of Halophenols and Phenol Boronic Acids: Systematic Investigation of Positional Isomer Effects and Conclusions for the Synthesis of Phytoalexins from Pyrinae
Schmidt, Bernd; Riemer, Martin, Journal of Organic Chemistry, 2014, 79(9), 4104-4118

合成路线:1 步

反应条件:
参考文献:
Preparation of biphenols by oxidative coupling of alkylphenols using a recyclable copper catalyst
, World Intellectual Property Organization, , ,

合成路线:1 步

反应条件:
参考文献:
Preparation of tetraalkylbiphenols by the oxidative coupling of dialkylphenols using a copper-amino complex catalyst
, United States, , ,

合成路线:1 步

反应条件:
参考文献:
Steroid analogs lacking ring C. III. Synthesis of 4-(trans-4-hydroxycyclohexyl)cyclohexanone
Wilds, A. L.; Shunk, Clifford H.; Hoffman, Carl H., Journal of the American Chemical Society, 1954, 76, 1733-6

合成路线:1 步

反应条件:
参考文献:
Microwave-assisted aqueous carbon-carbon cross-coupling reactions of aryl chlorides catalysed by reduced graphene oxide supported palladium nanoparticles
Zhang, Qingxiao; Mao, Zhan; Wang, Kaixuan; Phan, Nam Thanh Son; Zhang, Fang, Green Chemistry, 2020, 22(10), 3239-3247

合成路线:1 步

反应条件:
参考文献:
Hydroxylation-Depolymerization of Oxyphenylene-Based Super Engineering Plastics To Regenerate Arenols
Minami, Yasunori ; et al, JACS Au, 2023, 3(8), 2323-2332

合成路线:1 步

反应条件:
参考文献:
N-hydroxyphthalimide
Gambarotti, Cristian; Punta, Carlo; Recupero, Francesco; Zlotorzynska, Maria; Sammis, Glenn, e-EROS Encyclopedia of Reagents for Organic Synthesis, 2013, 1, 1-9

合成路线:1 步

反应条件:
参考文献:
A Highly Active Heterogeneous Palladium Catalyst for the Suzuki-Miyaura and Ullmann Coupling Reactions of Aryl Chlorides in Aqueous Media
Yuan, Bizhen; Pan, Yingyi; Li, Yingwei; Yin, Biaolin; Jiang, Huanfeng, Angewandte Chemie, 2010, 49(24), 4054-4058

合成路线:1 步

反应条件:
参考文献:
Palladium-Catalyzed Inter- and Intramolecular Coupling Reactions of Aryl and Vinyl Halides Mediated by Indium
Lee, Phil Ho; Seomoon, Dong; Lee, Kooyeon, Organic Letters, 2005, 7(2), 343-345

合成路线:1 步

反应条件:
参考文献:
Palladium-S-propyl-2-aminobenzothioate immobilized on Fe3O4 magnetic nanoparticles as catalyst for Suzuki and Heck reactions in water or poly(ethylene glycol)
Ghorbani-Choghamarani, Arash; Tahmasbi, Bahman; Moradi, Parisa, Applied Organometallic Chemistry, 2016, 30(6), 422-430

合成路线:1 步

反应条件:
参考文献:
Organic synthesis via magnetic attraction: benign and sustainable protocols using magnetic nanoferrites
Nasir Baig, R. B.; Varma, Rajender S., Green Chemistry, 2013, 15(2), 398-417

合成路线:1 步

反应条件:
参考文献:
Preparation of tetraalkylbiphenols by the oxidative coupling of dialkylphenols using a recyclable cuprous halide-diamine complex catalyst
, United States, , ,

合成路线:1 步

反应条件:
参考文献:
Facile synthesis of magnetic recyclable palladium-gold alloy nanoclusters catalysts PdAur/Fe3O4@LDH and its catalytic applications in Heck reaction
Li, Jin; Wang, Yajuan; Jiang, Shunwang; Zhang, Hui, Journal of Organometallic Chemistry, 2018, 878, 84-95

合成路线:1 步

反应条件:
参考文献:
Green method for synthesis of 4,4-biphenol
, China, , ,

合成路线:1 步

反应条件:
参考文献:
The copper-catalyzed hydrolysis of 4,4'-dibromobiphenyl derivatives
Hanaoka, Takaaki; Yoshihiro, Sugi; Uchi, Kazutaka; Abe, Yoshimoto; Misono, Takahisa, Sekiyu Gakkaishi, 1994, 37(3), 328-32

合成路线:1 步

反应条件:
参考文献:
"Benchtop" Biaryl Coupling Using Pd/Cu Cocatalysis: Application to the Synthesis of Conjugated Polymers
Minus, Matthew B. ; Moor, Sarah R. ; Pary, Fathima F.; Nirmani, L. P. T.; Chwatko, Malgorzata; et al, Organic Letters, 2021, 23(8), 2873-2877

合成路线:1 步

反应条件:
参考文献:
Facile and efficient protocols for C-C and C-N bond formation reactions using a superparamagnetic palladium complex as reusable catalyst
Karimi Zarchi, Mohammad Ali; Darbandizadeh Mohammad Abadi, Seyed Shahab Addin, Research on Chemical Intermediates, 2019, 45(5), 2605-2639

合成路线:1 步

反应条件:
参考文献:
Cu(II)-catalyzed homocouplings of (hetero)arylboronic acids with the assistance of 2-O-methyl-D-glucopyranose
Yuan, Chunling; Zheng, Li; Zhao, Yingdai, Molecules, 2019, 24(20),
相关文献
专业数据库参考
PubChemId 24863103
参考资料
Reaxys RN 1908886
Beilstein 1908886
化合物详情(旧版)

物理化学性质

熔点278-283°C 水溶性sparingly soluble

产品用途

用作橡胶和乳胶的防老剂,可用于浅色橡胶制品、食品包装用胶和医用乳胶制品

应用领域







化学品安全说明书(MSDS)



储运特性





产品用途
用作橡胶和乳胶的防老剂,可用于浅色橡胶制品、食品包装用胶和医用乳胶制品
4,4'-二羟基联苯推荐生产厂家
960化工网为您提供4,4'-二羟基联苯专业化合物百科信息,包括中文名,英文名,分子式,分子量,以及该化合物的CasNo.:92-88-6,和相关理化性质;并提供了优质生产厂家信息包括厂家名称和联系方式等;| WAP 版:92-88-6
平台客服 平台客服

平台在线客服