2,6-二甲氧基苯酚 | 91-10-1

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中文名称：2,6-二甲氧基苯酚
英文名称：2,6-Dimethoxyphenol
CAS No.：91-10-1 分子式：C₈H₁₀O₃ 分子量：154.163202762604
如需查看该化合物的详细结构式,mol文件,smile, InChi 请点击：2,6-二甲氧基苯酚结构式
MSDS：2,6-二甲氧基苯酚msds 价格行情：2,6-二甲氧基苯酚价格 PubChem CID：87567285
国内供应商

2,6-二甲氧基苯酚的其他展现形式

相关化合物

愈创木酚 2-Methoxyphenol CAS No.：90-05-1

甲氧基对苯二酚 2-Methoxybenzene-1,4-diol CAS No.：824-46-4

3,4-二甲氧基苯酚 3,4-Dimethoxyphenol CAS No.：2033-89-8

3,4,5-三甲氧基苯酚 3,4,5-Trimethoxyphenol CAS No.：642-71-7

1,2,4-三甲氧基苯 1,2,4-Trimethoxybenzene CAS No.：135-77-3

1,2,3-三甲氧基苯 1,2,3-Trimethoxybenzene CAS No.：634-36-6

简介

2,6-Dimethoxyphenol 是一种酚类化合物，广泛用于漆酶活性的测定。

名称和标识符

MDL	MFCD00064434
InChIKey	KLIDCXVFHGNTTM-UHFFFAOYSA-N
Inchi	1S/C8H10O3/c1-10-6-4-3-5-7(11-2)8(6)9/h3-5,9H,1-2H3
SMILES	OC1C(OC)=CC=CC=1OC
BRN	1526871

别名信息

- 中文别名 -

2,6-二甲氧基苯酚邻苯三酚-1,3-二甲醚 2,6-Dimethoxyphenol 2,6-二甲氧基苯酚 2,6-二甲氧基苯 2,6-二甲氧基苯酚,2,6-Dimethoxyphenol 2,6-二甲氧基苯酚标准品 2,6-二甲氧基酚 WAKO047-306812,6-二甲氧基苯酚标准品焦性儿茶酚-1,3-二甲醚邻苯三酚1,3-二甲醚紫丁紫丁香醇邻苯三酚 1,3-二甲醚

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- 英文别名 -

2,6-Dimethoxyphenol Pyrogallol 1,3-dimethyl ether~Syringol Syringol 1,3-dimethoxy-2-hydroxybenzene 1,3-dimethylpyrogallate 2,5-DIIODO-4-METHYL-1H-IMIDAZOLE 2,6-dimethoxy-pheno 2,6-Dimethoxyphenyl 2,6-Dwumetoksyfenol Dimethoxyphenol MCP Phenol,2,6-dimethoxy Pyrogallol 1,3-dimethyl ether Pyrogallol-1,3-diMethyl ether 2-Hydroxy-1,3-dimethoxybenzene Pyrogallol 1,3-dimethylether 1,3-Dimethyl pyrogallate Phenol, 2,6-dimethoxy- Aldrich 1,3-Di-o-methylpyrogallol 2,6-dimethoxy-phenol Pyrogallol dimethylether 2,6-dimethoxy phenol 2,6-Dwumetoksyfenol [Polish] FEMA No. 3137 4UQT464H8K KLIDCXVFHGNTTM-UHFFFAOYSA-N 3DM 2,6-dim 2,6-Dimethoxyphenol (ACI) 1,3-Dimethoxy-2-hydroxybenzene 2,6-Dimethoxyphenic acid

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物化性质

实验特性

LogP	1.40940
PSA	38.69000
折射率	1.4745 (estimate)
水溶性	2 g/100 mL (13 ºC)
沸点	261 °C(lit.)
熔点	50-57 °C (lit.)
闪点	华氏：284 °F 摄氏：140 °C
FEMA	3137 \| 2,6-DIMETHOXYPHENOL
颜色与性状	Oil
溶解性	易溶于乙醚，溶于乙醇、碱溶液，微溶于水。
敏感性	对空气敏感
密度	1.1690 (rough estimate)

计算特性

精确分子量	154.06300
氢键供体数量	1
氢键受体数量	3
可旋转化学键数量	2
同位素质量	154.062994
重原子数量	11
复杂度	104
同位素原子数量	0
确定原子立构中心数量	0
不确定原子立构中心数量	0
确定化学键立构中心数量	0
不确定化学键立构中心数量	0
共价键单元数量	1
疏水参数计算参考值（XlogP）	1.1
互变异构体数量	2
表面电荷	0
拓扑分子极性表面积	38.7

安全信息纠错

符号：	GHS07
RTECS号	SL0900000
WGK Germany	3
安全说明	S26-S36-S37/39
风险术语	R22; R36/37/38
危险品标志	Xn
危险品运输编号	UN 2811 6.1/PG 1
危害声明	H302,H315,H319,H335
警示性声明	P261,P305+P351+P338
提示语	警告
储存条件	Inert atmosphere,Room Temperature
危险类别码	22-36/37/38
信号词	Warning
TSCA	Yes

国际标准相关数据

EINECS

202-041-1

海关数据

海关编码

2909500000

海关数据

中国海关编码：

2909500000

概述：

2909500000. 醚酚、醚醇酚及其卤化、磺化、硝化或亚硝化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

申报要素：

品名, 成分含量, 用途

Summary：

2909500000 ether-phenols, ether-alcohol-phenols and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

合成路线

合成路线：1 步

反应条件：查看详情

参考文献 :: Ligand enabled none-oxidative decarbonylation of aliphatic aldehydes

Li, Bo; Liu, Shihao; Fan, Wu; Shen, Xiaotong; Xu, Jing; et al, Chinese Chemical Letters, 2023, 34(7),

合成路线：1 步

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参考文献 :: A simple deprotection of triflate esters of phenol derivatives

Ohgiya, Tadaaki; Nishiyama, Shigeru, Tetrahedron Letters, 2004, 45(33), 6317-6320

合成路线：1 步

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参考文献 :: Mild cleavage of aryl mesylates. Methanesulfonate as potent protecting group for phenols

Ritter, Tobias; Stanek, Kyrill; Larrosa, Igor; Carreira, Erick M., Organic Letters, 2004, 6(9), 1513-1514

合成路线：1 步

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1.1 Catalysts: Cuprous iodide , Indion 770 Solvents: Dimethyl sulfoxide ; 10 min, 125 °C
1.2 Reagents: Cesium hydroxide Solvents: Water ; 6 h, 125 °C; 125 °C → rt
1.3 Reagents: Hydrochloric acid Solvents: Water ; acidified, rt

参考文献 :: Sulfonic acid resin and copper salts: a novel heterogeneous catalytic system for direct hydroxylation of haloarenes

Amal Joseph, P. J.; Priyadarshini, S.; Lakshmi Kantam, M.; Maheswaran, H., Catalysis Science & Technology, 2011, 1(4), 582-585

合成路线：1 步

1416781-15-1
_90%
91-10-1

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参考文献 :: Mechanochemical degradation of lignin and wood by solvent-free grinding in a reactive medium

Kleine, Tillmann; Buendia, Julien; Bolm, Carsten, Green Chemistry, 2013, 15(1), 160-166

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参考文献 :: Boron trichloride as a selective demethylating agent for hindered ethers

Carvalho, Christopher F.; Sargent, Melvyn V., Journal of the Chemical Society, 1984, (4), 227-9

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参考文献 :: Acid-Functionalised Magnetic Ionic Liquid [AcMIm]FeCl4 as Catalyst for Oxidative Hydroxylation of Arylboronic Acids and Regioselective Friedel-Crafts Acylation

Saha, Arijit ; Payra, Soumen; Dutta, Dipa; Banerjee, Subhash, ChemPlusChem, 2017, 82(8), 1129-1134

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参考文献 :: I. Cholesterol-Absorption Inhibitors II. Toward the Synthesis of (+)-Resiniferatoxin via Photorearrangement of Cross-Conjugated Cyclohexadienones

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参考文献 :: Preparation of 2,6-disubstituted phenols by thermal decarboxylation of 2,6-disubstituted-4-hydroxybenzoic acids

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Kabalka, George W.; Reddy, N. Kesavulu; Narayana, Chatla, Tetrahedron Letters, 1993, 34(48), 7667-8

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Krow, Grant R., Organic Reactions (Hoboken, 1993, 43,

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参考文献 :: A scalable and green one-minute synthesis of substituted phenols

Elumalai, Vijayaragavan; Hansen, Joern H., RSC Advances, 2020, 10(66), 40582-40587

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参考文献 :: Preparation of pyrogallol from phenol

, Japan, , ,

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参考文献 :: Lewis acid-catalyzed deprotection of para-methoxybenzyl ether

Bouzide, Abderrahim; Sauve, Gilles, Synlett, 1997, (10), 1153-1154

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参考文献 :: Mild and Robust Redox-Neutral Pd/C-Catalyzed Lignol β-O-4' Bond Cleavage Through a Low-Energy-Barrier Pathway

Galkin, Maxim V.; Dahlstrand, Christian; Samec, Joseph S. M., ChemSusChem, 2015, 8(13), 2187-2192

合成路线：1 步

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参考文献 :: Copper MOF: scope and limitation in catalytic hydroxylation and nitration of aryl halides

Priyadarshini, S.; Amal Joseph, P. J.; Kantam, M. Lakshmi; Sreedhar, B., Tetrahedron, 2013, 69(31), 6409-6414

合成路线：1 步

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参考文献 :: Enhanced Acid-Catalyzed Lignin Depolymerization in a Continuous Reactor with Stable Activity

By Nandiwale, Kakasaheb Y. et al, ACS Sustainable Chemistry & Engineering, 2020, 8(10), 4096-4106

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专业数据库参考

PubChemId

87567285

参考资料

Reaxys RN	1526871
Beilstein	1526871