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2,6-二甲氧基苯酚 | 91-10-1

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中文名称:2,6-二甲氧基苯酚
英文名称:2,6-Dimethoxyphenol
CAS No.:91-10-1 分子式:C8H10O3 分子量:154.163202762604
如需查看该化合物的详细结构式,mol文件,smile, InChi 请点击:2,6-二甲氧基苯酚结构式
MSDS:2,6-二甲氧基苯酚msds 价格行情:2,6-二甲氧基苯酚价格 PubChem CID:87567285
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2,6-二甲氧基苯酚的其他展现形式
  • 相关化合物
愈创木酚 2-Methoxyphenol CAS No.:90-05-1
甲氧基对苯二酚 2-Methoxybenzene-1,4-diol CAS No.:824-46-4
3,4-二甲氧基苯酚 3,4-Dimethoxyphenol CAS No.:2033-89-8
3,4,5-三甲氧基苯酚 3,4,5-Trimethoxyphenol CAS No.:642-71-7
1,2,4-三甲氧基苯 1,2,4-Trimethoxybenzene CAS No.:135-77-3
1,2,3-三甲氧基苯 1,2,3-Trimethoxybenzene CAS No.:634-36-6
简介
2,6-Dimethoxyphenol 是一种酚类化合物,广泛用于漆酶活性的测定。
名称和标识符
MDL MFCD00064434
InChIKey KLIDCXVFHGNTTM-UHFFFAOYSA-N
Inchi 1S/C8H10O3/c1-10-6-4-3-5-7(11-2)8(6)9/h3-5,9H,1-2H3
SMILES OC1C(OC)=CC=CC=1OC
BRN 1526871
别名信息
- 中文别名 -
2,6-二甲氧基苯酚 邻苯三酚-1,3-二甲醚 2,6-Dimethoxyphenol 2,6-二甲氧基苯酚 2,6-二甲氧基苯 2,6-二甲氧基苯酚,2,6-Dimethoxyphenol 2,6-二甲氧基苯酚标准品 2,6-二甲氧基酚 WAKO047-306812,6-二甲氧基苯酚标准品 焦性儿茶酚-1,3-二甲醚 邻苯三酚1,3-二甲醚 紫丁 紫丁香醇 邻苯三酚 1,3-二甲醚
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- 英文别名 -
2,6-Dimethoxyphenol Pyrogallol 1,3-dimethyl ether~Syringol Syringol 1,3-dimethoxy-2-hydroxybenzene 1,3-dimethylpyrogallate 2,5-DIIODO-4-METHYL-1H-IMIDAZOLE 2,6-dimethoxy-pheno 2,6-Dimethoxyphenyl 2,6-Dwumetoksyfenol Dimethoxyphenol MCP Phenol,2,6-dimethoxy Pyrogallol 1,3-dimethyl ether Pyrogallol-1,3-diMethyl ether 2-Hydroxy-1,3-dimethoxybenzene Pyrogallol 1,3-dimethylether 1,3-Dimethyl pyrogallate Phenol, 2,6-dimethoxy- Aldrich 1,3-Di-o-methylpyrogallol 2,6-dimethoxy-phenol Pyrogallol dimethylether 2,6-dimethoxy phenol 2,6-Dwumetoksyfenol [Polish] FEMA No. 3137 4UQT464H8K KLIDCXVFHGNTTM-UHFFFAOYSA-N 3DM 2,6-dim 2,6-Dimethoxyphenol (ACI) 1,3-Dimethoxy-2-hydroxybenzene 2,6-Dimethoxyphenic acid
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物化性质
 实验特性
LogP 1.40940
PSA 38.69000
折射率 1.4745 (estimate)
水溶性 2 g/100 mL (13 ºC)
沸点 261 °C(lit.)
熔点 50-57 °C (lit.)
闪点 华氏:284 °F
摄氏:140 °C
FEMA 3137 | 2,6-DIMETHOXYPHENOL
颜色与性状 Oil
溶解性 易溶于乙醚,溶于乙醇、碱溶液,微溶于水。
敏感性 对空气敏感
密度 1.1690 (rough estimate)
 计算特性
精确分子量 154.06300
氢键供体数量 1
氢键受体数量 3
可旋转化学键数量 2
同位素质量 154.062994
重原子数量 11
复杂度 104
同位素原子数量 0
确定原子立构中心数量 0
不确定原子立构中心数量 0
确定化学键立构中心数量 0
不确定化学键立构中心数量 0
共价键单元数量 1
疏水参数计算参考值(XlogP) 1.1
互变异构体数量 2
表面电荷 0
拓扑分子极性表面积 38.7
国际标准相关数据
EINECS 202-041-1
海关数据
海关编码 2909500000
海关数据

中国海关编码:

2909500000

概述:

2909500000. 醚酚、醚醇酚及其卤化、磺化、硝化或亚硝化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

申报要素:

品名, 成分含量, 用途

Summary:

2909500000 ether-phenols, ether-alcohol-phenols and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

合成路线

合成路线:1 步

反应条件: 查看详情

参考文献 :
Ligand enabled none-oxidative decarbonylation of aliphatic aldehydes
Li, Bo; Liu, Shihao; Fan, Wu; Shen, Xiaotong; Xu, Jing; et al, Chinese Chemical Letters, 2023, 34(7),

合成路线:1 步

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参考文献 :
A simple deprotection of triflate esters of phenol derivatives
Ohgiya, Tadaaki; Nishiyama, Shigeru, Tetrahedron Letters, 2004, 45(33), 6317-6320

合成路线:1 步

反应条件: 查看详情

参考文献 :
Mild cleavage of aryl mesylates. Methanesulfonate as potent protecting group for phenols
Ritter, Tobias; Stanek, Kyrill; Larrosa, Igor; Carreira, Erick M., Organic Letters, 2004, 6(9), 1513-1514

合成路线:1 步

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参考文献 :
Sulfonic acid resin and copper salts: a novel heterogeneous catalytic system for direct hydroxylation of haloarenes
Amal Joseph, P. J.; Priyadarshini, S.; Lakshmi Kantam, M.; Maheswaran, H., Catalysis Science & Technology, 2011, 1(4), 582-585

合成路线:1 步

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参考文献 :
Mechanochemical degradation of lignin and wood by solvent-free grinding in a reactive medium
Kleine, Tillmann; Buendia, Julien; Bolm, Carsten, Green Chemistry, 2013, 15(1), 160-166

合成路线:1 步

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参考文献 :
Boron trichloride as a selective demethylating agent for hindered ethers
Carvalho, Christopher F.; Sargent, Melvyn V., Journal of the Chemical Society, 1984, (4), 227-9

合成路线:1 步

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参考文献 :
Acid-Functionalised Magnetic Ionic Liquid [AcMIm]FeCl4 as Catalyst for Oxidative Hydroxylation of Arylboronic Acids and Regioselective Friedel-Crafts Acylation
Saha, Arijit ; Payra, Soumen; Dutta, Dipa; Banerjee, Subhash, ChemPlusChem, 2017, 82(8), 1129-1134

合成路线:1 步

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参考文献 :
I. Cholesterol-Absorption Inhibitors II. Toward the Synthesis of (+)-Resiniferatoxin via Photorearrangement of Cross-Conjugated Cyclohexadienones
Ritter, Tobias, 2004, , ,

合成路线:1 步

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参考文献 :
Preparation of 2,6-disubstituted phenols by thermal decarboxylation of 2,6-disubstituted-4-hydroxybenzoic acids
, Czechoslovakia, , ,

合成路线:1 步

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参考文献 :
Sodium perborate: a convenient reagent for benzylic hydroperoxide rearrangement
Kabalka, George W.; Reddy, N. Kesavulu; Narayana, Chatla, Tetrahedron Letters, 1993, 34(48), 7667-8

合成路线:1 步

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参考文献 :
The Baeyer-Villiger oxidation of ketones and aldehydes
Krow, Grant R., Organic Reactions (Hoboken, 1993, 43,

合成路线:1 步

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参考文献 :
A scalable and green one-minute synthesis of substituted phenols
Elumalai, Vijayaragavan; Hansen, Joern H., RSC Advances, 2020, 10(66), 40582-40587

合成路线:1 步

反应条件: 查看详情

参考文献 :
Preparation of pyrogallol from phenol
, Japan, , ,

合成路线:1 步

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参考文献 :
Lewis acid-catalyzed deprotection of para-methoxybenzyl ether
Bouzide, Abderrahim; Sauve, Gilles, Synlett, 1997, (10), 1153-1154

合成路线:1 步

反应条件: 查看详情

参考文献 :
Mild and Robust Redox-Neutral Pd/C-Catalyzed Lignol β-O-4' Bond Cleavage Through a Low-Energy-Barrier Pathway
Galkin, Maxim V.; Dahlstrand, Christian; Samec, Joseph S. M., ChemSusChem, 2015, 8(13), 2187-2192

合成路线:1 步

反应条件: 查看详情

参考文献 :
Copper MOF: scope and limitation in catalytic hydroxylation and nitration of aryl halides
Priyadarshini, S.; Amal Joseph, P. J.; Kantam, M. Lakshmi; Sreedhar, B., Tetrahedron, 2013, 69(31), 6409-6414

合成路线:1 步

反应条件: 查看详情

参考文献 :
The Baeyer-Villiger oxidation of aromatic aldehydes and ketones with hydrogen peroxide catalyzed by selenium compounds. A convenient method for the preparation of phenols
Syper, Ludwik, Synthesis, 1989, (3), 167-72

合成路线:1 步

更多

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参考文献 :
Enhanced Acid-Catalyzed Lignin Depolymerization in a Continuous Reactor with Stable Activity
By Nandiwale, Kakasaheb Y. et al, ACS Sustainable Chemistry & Engineering, 2020, 8(10), 4096-4106

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专业数据库参考
PubChemId 87567285
参考资料
Reaxys RN 1526871
Beilstein 1526871
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