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二苯甲胺 | 91-00-9

二苯甲胺
diphenylmethanamine
91-00-9
C13H13N
183.249023199081
如需查看该化合物的详细结构式,mol文件,smile,InChi 请点击:二苯甲胺结构式
7036
二苯甲胺价格
简介
        二苯甲胺(Diphenylmethanamine)强碱性。在空气中能吸收二氧化碳而形成一种在91℃时熔融的物质,有机合成和医药中间体。
名称和标识符
MDL MFCD00008059
InChIKey MGHPNCMVUAKAIE-UHFFFAOYSA-N
Inchi 1S/C13H13N/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,13H,14H2
SMILES NC(C1C=CC=CC=1)C1C=CC=CC=1
BRN 776434
别名信息
- 中文别名 -
  • 二苯甲胺
  • 氨基二苯甲烷
  • 甲基胺二苯
  • 二苯甲胺 OR 氨基二苯甲烷
  • 1,1-二苯基甲胺
  • Α-氨基二苯基甲烷
  • Α-苯基苯甲胺
  • 二苯甲基胺
  • Benzhydrylamine
  • 二苯甲基胺
  • 氨基二苯基甲烷
  • α-氨基二苯甲烷
  • 二本甲胺
  • α-氨基二苯基甲烷
- 英文别名 -
  • Diphenylmethanamine
  • Benzhydrylamine
  • Phenylbenzenemethanamine
  • alpha-phenyl-benzenemethanamin
  • alpha-phenylbenzenemethanamine
  • alpha-Phenylbenzylamine
  • Benzenemethanamine, alpha-phenyl-
  • Methanamine, 1,1-diphenyl-
  • Methylamine, 1,1-diphenyl-
  • 1,1-DIPHENYLMETHYLAMINE
  • Aminodiphenylmethane
  • Benzenemethanamine,a-phenyl-
  • C,C-Diphenyl-methylamine
  • α-Aminodiphenylmethane
  • (Diphenylmethyl)amine
  • 1,1-diphenylmethanamine
  • benzhydryl amine
  • alpha-Aminodiphenylmethane
  • Benzenemethanamine, .alpha.-phenyl-
  • .alpha.-Phenylbenzylamine
  • 4BO6ISS9DX
  • .alpha.-Aminodiphenylmethane
  • MGHPNCMVUAKAIE-UHFFFAOYSA-N
  • PB10011
  • CS-D1366
  • Methylamine,1-diphenyl-
  • C,C-diphenylmethylamine
  • NSC-49127
  • Benzhydrylamine, purum, >=97.0% (GC)
  • aminodiphenyl methane
  • HMS1785L01
  • aminodiphenyl-methane
  • Benzhydrylamine, 97%
  • SCHEMBL7841
  • AS-12859
  • FT-0622663
  • benzhydrylamin-
  • 1,1-Diphenylmethylamine
  • B0124
  • BP-11378
  • BCP18638
  • NSC49127
  • Methanamine,1-diphenyl-
  • A25935
  • Q-200624
  • F0850-6748
  • STK801347
  • Methylamine, 1,1-diphenyl- (6CI,7CI,8CI)
  • BENZHYDRYLAMINE [MI]
  • 91-00-9
  • EINECS 202-032-2
  • BBL009929
  • Amikacin sulfate, Antibiotic for Culture Media Use Only
  • alpha-phenyl-benzenemethanamin
  • alpha-phenylbenzenemethanamine
  • InChI=1/C13H13N/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,13H,14H
  • SCHEMBL1573580
  • LS-30514
  • UNII-4BO6ISS9DX
  • BENZHYDRYLAMINE
  • AKOS000120236
  • CHEMBL467503
  • Ph2CHNH2
  • NSC 49127
  • diphenyl-methanamine
  • DTXSID00238346
  • Oprea1_187555
  • diphenylmethyamine
  • c,c-diphenyl-methylamine
  • Q27259384
  • MFCD00008059
  • benzhydryl-amine
  • EN300-15665
  • AMY10403
  • diphenylmethanamine
  • Q-103472
  • 1,1-diphenyl methylamine
  • alpha-Phenylbenzenemethanamine
  • Methylamine, 1,1-diphenyl- (6CI, 7CI, 8CI)
  • α-Phenylbenzenemethanamine (ACI)
  • 1,1-Diphenylmethanamine
  • 1-Amino-1-(phenylmethyl)benzene
  • Diphenylmethamine
  • α-Phenylbenzylamine
物化性质
实验特性
LogP 3.43500
PSA 26.02000
Merck 1076
折射率 n20/D 1.595(lit.)
水溶性 Miscible with chloroform, dimethylsulfoxide and methanol. Slightly miscible with water.
沸点 304°C(lit.)
熔点 12 °C (lit.)
闪点 华氏:235.4 °F
摄氏:113 °C
颜色与性状 无色六方薄片或液体
溶解性 微溶于水
敏感性 Air Sensitive
密度 1.063 g/mL at 25 °C(lit.)
计算特性
精确分子量 183.10500
氢键供体数量 1
氢键受体数量 1
可旋转化学键数量 2
同位素质量 183.105
重原子数量 14
复杂度 137
同位素原子数量 0
确定原子立构中心数量 0
不确定原子立构中心数量 0
确定化学键立构中心数量 0
不确定化学键立构中心数量 0
共价键单元数量 1
疏水参数计算参考值(XlogP) 2.4
互变异构体数量
表面电荷 0
拓扑分子极性表面积 26
国际标准相关数据
EINECS 49127
海关数据
海关数据

中国海关编码:

2921499090

概述:

2921499090 其他芳香单胺及衍生物及它们的盐. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%

申报要素:

品名, 成分含量, 用途

Summary:

2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

生产方法和用途
用途

有机合成和医药中间体。

合成路线

合成路线:1 步

反应条件:
参考文献:
Transfer Hydrogenation of Imines with Ammonia-Borane: A Concerted Double-Hydrogen-Transfer Reaction
Yang, Xianghua; Zhao, Lili; Fox, Thomas; Wang, Zhi-Xiang; Berke, Heinz, Angewandte Chemie, 2010, 49(11), 2058-2062

合成路线:1 步

反应条件:
参考文献:
Mild and chemoselective cleavage of p-nitrobenzyl esters and p-nitrobenzyloxycarbonylamines with zinc dust
Kumagai, Toshio; Abe, Takao; Fujimoto, Yukari; Hayashi, Takaaki; Inoue, Yoshinori; et al, Heterocycles, 1993, 36(8), 1729-34

合成路线:1 步

反应条件:
参考文献:
Synthesis of secondary and tertiary carbinamines from N-(trimethylsilyl)imines and organolithium reagents
Hirao, Akira; Hattori, Iwakazu; Yamaguchi, Kazuo; Nakahama, Seiichi; Yamazaki, Noboru, Synthesis, 1982, (6), 461-2

合成路线:1 步

反应条件:
参考文献:
A rapid and practical protocol for solvent-free reduction of oximes to amines with NaBH4/ZrCl4/Al2O3 system
Zeynizadeh, Behzad; Kouhkan, Mehri, Bulletin of the Korean Chemical Society, 2011, 32(9), 3448-3452

合成路线:1 步

反应条件:
参考文献:
Indium-mediated reduction of nitro and azide groups in the presence of HCl in aqueous media
Lee, Jung Gyu; Choi, Kyung Il; Koh, Hun Yeong; Kim, Youseung; Kang, Yonghan; et al, Synthesis, 2001, (1), 81-84

合成路线:1 步

反应条件:
参考文献:
Experimental and computational studies of borohydride catalyzed hydrosilylation of a variety of C:O and C:N functionalities including esters, amides and heteroarenes
Manas, Michael G.; Sharninghausen, Liam S.; Balcells, David; Crabtree, Robert H., New Journal of Chemistry, 2014, 38(4), 1694-1700

合成路线:1 步

反应条件:
参考文献:
Deprotection of a primary Boc group under basic conditions
Tom, Norma J.; Simon, Wendy M.; Frost, Heather N.; Ewing, Marcus, Tetrahedron Letters, 2004, 45(5), 905-906

合成路线:1 步

反应条件:
参考文献:
ROMPgel-Supported Triphenylphosphine with Potential Application in Parallel Synthesis
Aarstad, Erik; Barrett, Anthony G. M.; Hopkins, Brian T.; Koebberling, Johannes, Organic Letters, 2002, 4(11), 1975-1977

合成路线:1 步

反应条件:
参考文献:
Selective deprotection of allyl amines using palladium
Lemaire-Audoire, Sandrine; Savignac, Monique; Genet, Jean Pierre; Bernard, Jean-Marie, Tetrahedron Letters, 1995, 36(8), 1267-70

合成路线:1 步

反应条件:
参考文献:
α-Phenyl-benzenemethanamine and α-phenyl-benzenemethanamine hydrochloride
Pigza, Julie A., e-EROS Encyclopedia of Reagents for Organic Synthesis, 2011, 1, 1-4

合成路线:1 步

反应条件:
参考文献:
Synthesis of substituted benzhydrylamines
Dejaegher, Yves; Mangelinckx, Sven; De Kimpe, Norbert, Synlett, 2002, (1), 113-115

合成路线:1 步

反应条件:
参考文献:
Lewis acid-catalyzed nucleophilic substitutions of benzylic alcohols with sulfamides
Oda, Ryoga; Nakata, Kenya, European Journal of Organic Chemistry, 2021, 2021(2), 295-301

合成路线:1 步

反应条件:
参考文献:
Rearrangements of some new hydroxamic acids related to heterocyclic acids and to diphenyl- and triphenylacetic acids
Jones, Lauder W.; Hurd, Charles D., Journal of the American Chemical Society, 1921, 43, 2422-48

合成路线:1 步

反应条件:
参考文献:
Rapid deprotection of N-Boc amines by TFA combined with free base generation using basic ion-exchange resins
Srinivasan, Natarajan; Yurek-George, Alexander; Ganesan, A., Molecular Diversity, 2005, 9(4), 291-293

合成路线:1 步

反应条件:
参考文献:
Preparation and application of odorless 1,3-propanedithiol reagents
Matoba, Manabu; Kajimoto, Tetsuya; Nishide, Kiyoharu; Node, Manabu, Chemical & Pharmaceutical Bulletin, 2006, 54(1), 141-146

合成路线:1 步

反应条件:
参考文献:
Convenient cleavage of water-insoluble allylic substrates in the presence of per(2,6-di-O-methyl)-β-cyclodextrin
Widehem, Rodrigue; Lacroix, Thibaut; Bricout, Herve; Monflier, Eric, Synlett, 2000, (5), 722-724

合成路线:1 步

反应条件:
参考文献:
The efficient solvent-free reduction of oximes to amines with NaBH3CN catalyzed by ZrCl4/nano Fe3O4 system
Sadighnia, Leila; Zeynizadeh, Behzad, Journal of the Iranian Chemical Society, 2015, 12(5), 873-878

合成路线:1 步

反应条件:
参考文献:
Photochemical oxidation of imines
Toshima, Naoki; Hirai, Hidefumi, Tetrahedron Letters, 1970, (6), 433-6
相关文献
专业数据库参考
PubChemId 7036
参考资料
Reaxys RN 776434
Beilstein 12,1323
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