1.1
Catalysts:
Bis(1,5-cyclooctadiene)nickel
,
(3aR,8aR)-4,4,8,8-Tetrakis(3,5-dimethylphenyl)-6-[2-(diphenylphosphino)-6-(1-met…
Solvents:
Toluene
;
1 min, rt
1.2
10 h, 80 °C
2.1
Reagents:
Diisobutylaluminum hydride
Solvents:
Diethyl ether
,
Hexane
;
0.5 h, -40 °C
2.2
Reagents:
Sodium borohydride
Solvents:
Ethanol
;
0 °C; 0 °C → rt; overnight, rt
2.3
Reagents:
Ammonium chloride
Solvents:
Water
;
rt
3.1
Reagents:
Sodium periodate
Catalysts:
Ruthenium trichloride
Solvents:
Carbon tetrachloride
,
Acetonitrile
,
Water
;
3 h, rt