1.1
Reagents:
tert-Butyl peroxide
Catalysts:
Tris[(11bR)-2,6-bis[4-(1,1-dimethylethyl)phenyl]-4-(hydroxy-κO)dinaphtho[2,1-d:1…
Solvents:
1,2-Dichloroethane
,
1,1,1,3,3,3-Hexafluoro-2-propanol
;
72 h, rt
2.1
Reagents:
Sodium hydride
Solvents:
Dimethylformamide
,
Tetrahydrofuran
;
0 °C; 2 h, rt
2.2
rt; 6 h, rt
3.1
Reagents:
Butyllithium
Solvents:
Tetrahydrofuran
,
Hexane
;
-78 °C; 30 min, -78 °C; 2 h, 0 °C; 0 °C → -78 °C
3.2
Reagents:
Iodine
;
-78 °C; 2 h, rt
3.3
Reagents:
Sodium thiosulfate
Solvents:
Water
;
rt
4.1
Reagents:
Sodium hydroxide
Catalysts:
Tetrakis(triphenylphosphine)palladium
Solvents:
Tetrahydrofuran
,
Water
;
6 h, 80 °C
5.1
Reagents:
Hydrochloric acid
Solvents:
1,4-Dioxane
,
Water
;
rt; rt → 90 °C; 3 h, 90 °C
6.1
Reagents:
Phosphorus oxychloride
Solvents:
Pyridine
;
rt; 10 min, rt; 2 h, 90 °C; 90 °C → rt
6.2
Reagents:
Water
;
rt; 2 h, 90 °C