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1-十一烯 | 821-95-4

1-十一烯
1-Undecene
821-95-4
C11H22
154.292383670807
如需查看该化合物的详细结构式,mol文件,smile,InChi 请点击:1-十一烯结构式
1-十一烯MSDS
87575854
1-十一烯价格
简介
WinID:07R9中文名称:1-十一烯 英文名称:1-Undecene 别名名称:正-1-十一碳烯;a-十一碳烯 更多别名:n-1-Undecene a-Undecene
分子式:C11H22 结构式:CH3(CH2)8CH=CH2
分子量:154.29
名称和标识符
MDL MFCD00008956
InChIKey DCTOHCCUXLBQMS-UHFFFAOYSA-N
Inchi 1S/C11H22/c1-3-5-7-9-11-10-8-6-4-2/h3H,1,4-11H2,2H3
SMILES C=CCCCCCCCCC
别名信息
- 中文别名 -
  • 1-十一烯
  • 1-十一烯[标准物质]
  • 1-Undecene 1-十一烯
  • 1-Undecene [Standard Material for GC] 1-十一烯[标准物质]
  • 1-十一碳烯
  • 1-Undecene,certified 标准品
  • 1-癸烯
  • 1-十一烷烯
- 英文别名 -
  • 1-Undecene
  • 1-Undecene [Standard Material for GC]
  • undec-1-ene
  • 1-Hendecene
  • 1-Undecene [Standard Material]
  • 1-Undecene100µg
  • cis-undecene
  • n-1-Undecene
  • NSC 73983
  • α-Undecene
  • Undec-1-ene
  • 1-UNDECENE [HSDB]
  • NS00038169
  • .ALPHA.-NONYLETHYLENE
  • DTXCID0048268
  • U0052
  • D92764
  • ?1-UNDECENE
  • alpha-Nonylethylene
  • 68526-57-8
  • 1-UNDECENE
  • EINECS 212-483-7
  • Hendecene
  • 3,4-dichlorophenethylalcohol
  • NSC73983
  • 1446756A8F
  • AKOS009156849
  • U0025
  • 1-Undecene, 97%
  • Q14745306
  • MFCD00008956
  • Undecene-1
  • CCRIS 5720
  • LS-14020
  • CHEBI:77444
  • FT-0608327
  • DTXSID5061168
  • Undecene
  • alpha-Undecene
  • LMFA11000332
  • HSDB 1090
  • EINECS 271-214-1
  • EC 271-214-1
  • 821-95-4
  • alpha-Undecylene
  • UNII-1446756A8F
  • .alpha.-Undecene
  • NSC-73983
  • N-NONYLETHYLENE
  • .ALPHA.-UNDECYLENE
物化性质
实验特性
LogP 4.31310
PSA 0.00000
折射率 n20/D 1.426(lit.)
水溶性 Solunle in ether, chloroform and ligroin. Insoluble in water.
沸点 193°C(lit.)
熔点 −49 °C (lit.)
闪点 华氏:145.4 °F
摄氏:63 °C
颜色与性状 无色液体
溶解性 不溶于水,溶于有机溶剂。
密度 0.75 g/mL at 25 °C(lit.)
计算特性
精确分子量 154.17200
氢键供体数量 0
氢键受体数量 0
可旋转化学键数量 8
同位素质量 154.172151
重原子数量 11
复杂度 74.1
同位素原子数量 0
确定原子立构中心数量 0
不确定原子立构中心数量 0
确定化学键立构中心数量 0
不确定化学键立构中心数量 0
共价键单元数量 1
疏水参数计算参考值(XlogP)
互变异构体数量
表面电荷 0
拓扑分子极性表面积 0
国际标准相关数据
EINECS 212-483-7
合成路线

合成路线:1 步

反应条件:
参考文献:
Piperazine-promoted gold-catalyzed hydrogenation: the influence of capping ligands
Fiorio, Jhonatan L.; et al, Catalysis Science & Technology, 2020, 10(7), 1996-2003

合成路线:1 步

反应条件:
参考文献:
Application of Groups 15 and 16 organoelement compounds in organic synthesis. Part 84. A novel methylenation method of aldehydes mediated by dibutyl telluride
Li, Saowei; et al, Chemische Berichte, 1990, 123(6), 1441-2

合成路线:1 步

参考文献:
Synthesis of alkenes by elimination reactions
Kostikov, R. R.; et al, Science of Synthesis, 2010, 47, 771-881

合成路线:1 步

反应条件:
参考文献:
Stereoselective Preparation of E Vinyl Zirconium Derivatives from E or Z Enol Ethers
Liard, Annie; et al, Journal of Organic Chemistry, 2000, 65(21), 7218-7220

合成路线:1 步

反应条件:
参考文献:
Regio- as well as stereoselective epoxide ring opening reactions using 3,3,3-trifluoroprop-1-yne
Yamazaki, Takashi ; et al, Journal of Fluorine Chemistry, 2022, 257, 257-258

合成路线:1 步

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参考文献:
Preparation of Primary and Secondary Dialkylmagnesiums by a Radical I/Mg-Exchange Reaction Using sBu2Mg in Toluene
Sunagatullina, Alisa S.; et al, Angewandte Chemie, 2022, 61(13),

合成路线:1 步

反应条件:
参考文献:
New method for the synthesis of olefins via β-hydroxyalkyl phenyl sulfides
Kuwajima, Isao; et al, Tetrahedron Letters, 1972, (9), 737-9

合成路线:1 步

反应条件:
参考文献:
Ligandless iron-catalyzed desulfinylative C-C allylation reactions using Grignard reagents and alk-2-enesulfonyl chlorides
Volla, Chandra M. R.; et al, European Journal of Organic Chemistry, 2009, (36), 6281-6288

合成路线:1 步

反应条件:
参考文献:
Palladium-catalyzed desulfinylative C-C allylation of Grignard reagents and enolates using allylsulfonyl chlorides and esters
Rao Volla, Chandra M.; et al, Tetrahedron, 2009, 65(2), 504-511

合成路线:1 步

反应条件:
参考文献:
Unsaturated sulfinamides. III. Conversion of several 4-(2'-alkenesulfinyl)morpholines into the corresponding sulfinate esters, unsymmetrical bisallylic sulfones, and olefins. Isolation of some functionalized 2-alkenesulfinic acids
Baudin, Jean Bernard; et al, Tetrahedron Letters, 1988, 29(26), 3255-8

合成路线:1 步

反应条件:
参考文献:
Novel nickel-catalyzed coupling reaction of allyl ethers with chlorosilanes, alkyl tosylates, or alkyl halides promoted by vinyl-Grignard reagent leading to allylsilanes or alkenes
Terao, Jun; et al, Advanced Synthesis & Catalysis, 2004, 346(13-15), 1674-1678

合成路线:1 步

反应条件:
参考文献:
Selectivities in organic reactions via π-allylpalladium complexes
Tsuji, Jiro, Pure and Applied Chemistry, 1989, 61(10), 1673-80

合成路线:1 步

反应条件:
参考文献:
A new reduction system: combination of sodium sulfide (sodium hydrosulfide) with phase transfer agent in a two-phase mixture. Reductive debromination of vic-dibromides to olefins
Nakayama, Juzo; et al, Tetrahedron Letters, 1983, 24(29), 3001-4

合成路线:1 步

参考文献:
Chemistry of alkali metal tetracarbonylferrates. Synthesis of amines and dehalogenation reactions by a polymer supported iron carbonyl complex
Boldrini, Gian Paolo; et al, Journal of Organometallic Chemistry, 1983, 243(2), 195-8

合成路线:1 步

反应条件:
参考文献:
Copper(I)-catalyzed reactions of organolithiums and Grignard reagents
Erdik, Ender, Tetrahedron, 1984, 40(4), 641-57

合成路线:1 步

反应条件:
参考文献:
Ionic and organometallic-catalyzed organosilane reductions
Larson, Gerald L.; et al, Organic Reactions (Hoboken, 2008, 71, 1-737

合成路线:1 步

反应条件:
参考文献:
Total synthesis and antifungal activity of (2S,3R)-2-aminododecan-3-ol
Vijai Kumar Reddy, T.; et al, Bioorganic & Medicinal Chemistry Letters, 2012, 22(14), 4678-4680

合成路线:1 步

反应条件:
参考文献:
Nickel-Decorated Graphene Oxide/Polyaniline Hybrid: A Robust and Highly Efficient Heterogeneous Catalyst for Hydrogenation of Terminal Alkynes
Panwar, Vineeta; et al, Industrial & Engineering Chemistry Research, 2015, 54(45), 11493-11499

合成路线:1 步

反应条件:
参考文献:
Allylmagnesium bromide-copper(I) iodide
Greco, Michael N., e-EROS Encyclopedia of Reagents for Organic Synthesis, 2001, 1,

合成路线:1 步

反应条件:
参考文献:
Preparation of 1-alkenes by the palladium-catalyzed hydrogenolysis of terminal allylic carbonates and acetates with formic acid-triethylamine
Tsuji, Jiro; et al, Synthesis, 1986, (8), 623-7

合成路线:1 步

反应条件:
参考文献:
Green Solvent for the Synthesis of Linear α-Olefins from Fatty Acids
Hopen Eliasson, Sondre H. ; et al, ACS Sustainable Chemistry & Engineering, 2019, 7(5), 4903-4911

合成路线:1 步

反应条件:
参考文献:
Unsaturated sulfinamides. XII. Substituted 4-(2-alkenesulfinyl)morpholines: preparation and conversion into the corresponding sulfinic acids and esters. Stereochemistry of olefin formation by hydrolytic desulfinylation of allylic sulfinamides
Baudin, Jean-Bernard; et al, Bulletin de la Societe Chimique de France, 1995, 132(2), 196-214

合成路线:1 步

参考文献:
Synthesis of alkenes by elimination reactions
Kostikov, R. R.; et al, Science of Synthesis, 2010, 47, 771-881

合成路线:1 步

反应条件:
参考文献:
Organocopper reagents: substitution, conjugate addition, carbo/metallocupration, and other reactions
Lipshutz, Bruce H.; et al, Organic Reactions (Hoboken, 1992, 41,

合成路线:1 步

反应条件:
参考文献:
Tandem Catalysis: Transforming Alcohols to Alkenes by Oxidative Dehydroxymethylation
Wu, Xuesong; et al, Journal of the American Chemical Society, 2018, 140(32), 10126-10130

合成路线:1 步

反应条件:
参考文献:
Copper-Catalyzed Alkyl-Alkyl Cross-Coupling Reactions Using Hydrocarbon Additives: Efficiency of Catalyst and Roles of Additives
Iwasaki, Takanori; et al, Journal of Organic Chemistry, 2014, 79(18), 8522-8532

合成路线:1 步

反应条件:
参考文献:
Alkylidenation of ketones by gem-dibromoalkane, SmI2, and Sm in the presence of catalytic amount of CrCl3
Matsubara, Seijiro; et al, Chemistry Letters, 1995, (4), 259-60

合成路线:1 步

反应条件:
参考文献:
Decomposition and electrophilic properties of nonfunctionalized monohalogenated carbenoids
Villieras, J.; et al, Bulletin de la Societe Chimique de France, 1985, (5), 837-43
专业数据库参考
PubChemId 87575854
参考资料
Reaxys RN 1740044
Beilstein 1(4)910
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