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氯铱酸(六水) | 16941-92-7

氯铱酸(六水)
Hydrogen Hexachloroiridate(IV) n-Hydrate
16941-92-7
Cl6HIr
405.942929983139
如需查看该化合物的详细结构式,mol文件,smile,InChi 请点击:氯铱酸(六水)结构式
氯铱酸(六水)MOL
名称和标识符
MDL MFCD00011328
InChIKey PVMMMVHZRGMXED-UHFFFAOYSA-I
Inchi 1S/6ClH.Ir/h6*1H;/q;;;;;;+4/p-5
SMILES [Ir+4]([Cl-])([Cl-])([Cl-])([Cl-])([Cl-])[Cl-].[H+]
别名信息
- 中文别名 -
  • 氯铱酸(六水)
  • 二氢六氯铱酸(六水)
  • 氯铱酸六水合物
  • 氯铱酸
  • 氯铱酸,氯铱酸溶液
  • 氯铱酸水合物
  • 氯铱酸有机溶液
  • 氯铱酸,二氢六氯铱酸
  • 氯铱酸液体
  • 氯铱酸晶体
  • 氯铱酸晶体粉
  • 二氢六氯铱酸
  • 六水合氯铱酸
  • 氯铱酸溶液(盐酸)
  • 氯铱酸(溶液)
  • (OC-6-11)-二氢六氯铱酸(2-)
- 英文别名 -
  • Iridium(IV) chloride dihydrochloride
  • Hydrogen hexachloroiridate (IV) hexahydrate
  • Hexachloroiridium acid hydrate
  • Dihydrogen hexachloroiridate
  • Hexachloroiridic acid hexahydrate
  • Iridium(IV)
  • hexachloroiridate
  • hexachloroiridicacid
  • chloride dihydrochloride
  • CHLORIRIDIC ACID SOLUTION
  • chloroiridicacid(h2ircl6)
  • hydrogen hexachloroiridate
  • Hexachloroiridicacidhydrate
  • Chloroiridic acid - solution
  • Chloroiridic acid
  • Hydrogen Hexachloroiridate(IV) n-Hydrate
  • hexachloro-iridate(2-dihydrogen
  • hydrogenhexachloroiridate(4+)
  • DIHYDROGEN HEXACHLOROIRIDATE (IV)
  • HEXACHLOROIRIDIC(IV)ACID HYDRATE
物化性质
实验特性
LogP 3.97620
PSA 55.38000
沸点 244.4±23.0 °C at 760 mmHg
熔点 65 ºC
蒸气压 0.0±0.5 mmHg at 25°C
闪点 102.3±10.6 °C
颜色与性状 未确定
溶解性 未确定
密度 1.02
计算特性
精确分子量 512.85500
氢键供体数量 0
氢键受体数量 0
可旋转化学键数量 0
重原子数量 7
复杂度 19.1
同位素原子数量 0
确定原子立构中心数量 0
不确定原子立构中心数量 0
确定化学键立构中心数量 0
不确定化学键立构中心数量 0
共价键单元数量 3
表面电荷 0
国际标准相关数据
EINECS 241-012-8
氯铱酸(六水) MSDS
基础信息
Name: Hydrogen hexachloroiridate(IV) hexahydrate approx. 40% Iridium Material Safety Data Sheet
Synonym: Chloriridic acid; Hexachloroiridic acid; Hydrogen hexachloroiridate(4+); Iridate(2-), hexachloro-, dihydrogen,; Iridate(2-), hexachloro-, dihydrogen, (OC-6-11)
CAS: 16941-92-7
Section 1 - Chemical Product ? MSDS Name:Hydrogen hexachloroiridate(IV) hexahydrate approx. 40% Iridium Material Safety Data Sheet
Synonym:Chloriridic acid; Hexachloroiridic acid; Hydrogen hexachloroiridate(4+); Iridate(2-), hexachloro-, dihydrogen,; Iridate(2-), hexachloro-, dihydrogen, (OC-6-11)

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
16941-92-7 Hydrogen hexachloroiridate(IV) hexahyd ca. 100 241-012-8
Hazard Symbols: XN
Risk Phrases: 36/37/38 40

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Limited evidence of a carcinogenic effect.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary edema.
Chronic:
Effects may be delayed.

Section 4 - FIRST AID MEASURES
? Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, or carbon dioxide. Do NOT get water inside containers.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
? Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Avoid contact with skin and eyes. Avoid ingestion and inhalation. Use with adequate ventilation.
Use only in a chemical fume hood.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 16941-92-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Crystals
Color: black
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: H2IrCl6.6H2O
Molecular Weight: 515.02

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions. Hygroscopic: absorbs moisture or water from the air.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Moisture, water, strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 16941-92-7: NO3592500 LD50/LC50:
Not available.
Carcinogenicity:
Hydrogen hexachloroiridate(IV) hexahydrate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 40 Limited evidence of a carcinogenic effect.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 16941-92-7: No information available.
Canada
CAS# 16941-92-7 is listed on Canada's DSL List.
CAS# 16941-92-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 16941-92-7 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A
化合物详情(旧版)

SMILES

[H+].[H+].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].Cl[Ir-2](Cl)(Cl)(Cl)(Cl)Cl

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