名称和标识符别名信息物化性质安全信息生产方法和用途相关文献参考资料化合物详情（旧版）相关分类相关产品

顺-二氯双(三苯基膦)铂(II) | 15604-36-1

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中文名称：顺-二氯双(三苯基膦)铂(II)

英文名称： Platinum(2+);triphenylphosphane;dihydrochloride

CAS No.： 15604-36-1

分子式： C₃₆H₃₂Cl₂P₂Pt

分子量： 792.5708

如需查看该化合物的详细结构式,mol文件,smile,InChi 请点击：顺-二氯双(三苯基膦)铂(II)结构式

MSDS：顺-二氯双(三苯基膦)铂(II)MSDS

价格行情：顺-二氯双(三苯基膦)铂(II)价格

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顺-二氯双(三苯基膦)铂(II)的其他展现形式

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名称和标识符

MDL	MFCD00010825
InChIKey	XAFJSPPHVXDRIE-UHFFFAOYSA-N
Inchi	1S/2C18H15P.2ClH.Pt/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h21-15H;2*1H;/q;;;;+2
SMILES	[Pt+2].Cl[H].Cl[H].P(C1C([H])=C([H])C([H])=C([H])C=1[H])(C1C([H])=C([H])C([H])=C([H])C=1[H])C1C([H])=C([H])C([H])=C([H])C=1[H].P(C1C([H])=C([H])C([H])=C([H])C=1[H])(C1C([H])=C([H])C([H])=C([H])C=1[H])C1C([H])=C([H])C([H])=C([H])C=1[H]

别名信息

- 中文别名 -

顺-二氯双(三苯基膦)铂(II)
顺式二(三苯基膦)二氯化铂(II)
二(三苯基膦)二氯化铂
双三苯基磷二氯化钯
顺-二氯双(三苯基膦)铂

顺-二(三苯基膦)二氯化铂
顺-二(三苯基膦)二氯化铂(II)

- 英文别名 -

cis-bis(triphenylphosphine)platinum(ii) dichloride
Dichlorobis(triphenylphosphine)platinum (II)
cis-Bis(triphenylphosphine)platinum(II) chloride
cis-Dichlorobis(triphenylphosphine)platinum(II)
cis-Dichlorobis(triphenylphosphite)platinum(II)

Trans-Dichlorobis(triphenyl-phosphine)Palladium(II)
dichloroplatinum,triphenylphosphane
Pt min
Pt(PPh3)2Cl2
Platinum(2+)
triphenylphosphane
dihydrochloride

物化性质

实验特性

LogP	0.89510
PSA	27.18000
水溶性	不溶
沸点	No data available
熔点	≥300 °C (lit.)
闪点	181.7 °C
溶解度	Slightly soluble in chloroform, hexane toluene
颜色与性状	白色结晶或米色固体。有吸湿性。在空气中稳定。
溶解性	未确定。
敏感性	Hygroscopic

计算特性

精确分子量	789.08500
氢键供体数量	2
氢键受体数量	0
可旋转化学键数量	6
同位素质量	791.1
重原子数量	41
复杂度	202
同位素原子数量	0
确定原子立构中心数量	0
不确定原子立构中心数量	0
确定化学键立构中心数量	0
不确定化学键立构中心数量	0
共价键单元数量	3
表面电荷	0
拓扑分子极性表面积	0

安全信息

符号：	GHS07
RTECS号	SP5680000
WGK Germany	3
安全术语	S26;S37/39
安全说明	26-37/39-36
风险术语	R22; R36/37/38
危险品标志	Xi
危险品运输编号	NONH for all modes of transport
危害声明	H315,H319,H335
警示性声明	P261,P305+P351+P338
储存条件	充氩储存
危险类别码	36/37/38
信号词	Warning

生产方法和用途

用途	有机合成。

相关文献

1. Geometrically isomeric Pt(ii)/Fe(ii)-based heterometallo-supramolecular polymers with organometallic ligands for electrochromism and the electrochemical switching of Raman scattering
Chanchal Chakraborty,Rakesh K. Pandey,Utpal Rana,Miki Kanao,Satoshi Moriyama,Masayoshi Higuchi J. Mater. Chem. C 2016 4 9428
2. Isoprene platinum(II) complexes from cis-dichlorobis(triphenylphosphine) platinum(II) and isopropenylacetylene. Crystal and molecular structures of trans-chloro(1-isopropenylvinyl)bis(triphenylphosphine)-platinum(II)–benzene (1/1) and trans-(isopropenylethynyl)(1-isopropenylvinyl)bis(triphenylphosphine)platinum(II)
Anita Furlani,Maria Vittoria Russo,Angiola Chiesi Villa,Amelia Gaetani Manfredotti,Carlo Guastini J. Chem. Soc. Dalton Trans. 1977 2154
3. A study of the generality of the reaction of diazomethane with halogenoplatinum(II) complexes in the preparation of (halogenomethyl)platinum(II) complexes
Robert McCrindle,Gilles J. Arsenault,Rajeev Farwaha,Mark J. Hampden-Smith,Richard E. Rice,Alan McAlees J. Chem. Soc. Dalton Trans. 1988 1773
4. Bis(phosphine)bis(tellurocarboxylato)-palladium(II) and -platinum(II) complexes: synthesis and crystal structure
Shinzi Kato,Osamu Niyomura,Yasuyuki Kawahara,Takahiro Kanda J. Chem. Soc. Dalton Trans. 1999 1677
5. Reactions of chloro-olefins and chloroalkanes with tetrakis(triphenylphosphine)platinum(0)
W. J. Bland,R. D. W. Kemmitt J. Chem. Soc. A 1968 1278
6. Index of subjects, 1976
J. Chem. Soc. Dalton Trans. 1977 2413
7. Molecular cage-bridged plasmonic structures with well-defined nanogaps as well as the capability of reversible and selective guest trapping
Chen Wang,Li Tian,Wei Zhu,Shiqiang Wang,Ning Gao,Kang Zhou,Xianpeng Yin,Wanlin Zhang,Liang Zhao,Guangtao Li Chem. Sci. 2018 9 889
8. Sensitized EuIII luminescence through energy transfer from PtM2 (M = Ag or Au) alkynyl chromophores in PtM2Eu2 heteropentanuclear complexes
Jia Li,Jin-Yun Wang,Zhong-Ning Chen J. Mater. Chem. C 2013 1 3661
9. Solution-processed OLEDs based on phosphorescent PtAu2 complexes with phenothiazine-functionalized acetylides
Xian-Chong Zeng,Jin-Yun Wang,Liang-Jin Xu,Hui-Min Wen,Zhong-Ning Chen J. Mater. Chem. C 2016 4 6096
10. Using phosphorescent PtAu3 clusters for superior solution-processable organic light emitting diodes with very small efficiency roll-off
Nagarajan Natarajan,Lin-Xi Shi,Hui Xiao,Jin-Yun Wang,Li-Yi Zhang,Xu Zhang,Zhong-Ning Chen J. Mater. Chem. C 2018 6 8966

参考资料

Reaxys RN

化合物详情（旧版）

SMILES

Cl[Pt]Cl.C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3

顺-二氯双(三苯基膦)铂(II) | 15604-36-1

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