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硫酸锆 | 14644-61-2

硫酸锆
Zirconium sulfate
14644-61-2
2[O4S-2].Zr+4
283.3492
如需查看该化合物的详细结构式,mol文件,smile,InChi 请点击:硫酸锆结构式
硫酸锆MOL
名称和标识符
InChIKey ZXAUZSQITFJWPS-UHFFFAOYSA-J
Inchi InChI=1S/2H2O4S.Zr/c2*1-5(2,3)4;/h2*(H2,1,2,3,4);/q;;+4/p-4
SMILES S([O-])([O-])(=O)=O.[Zr+4].S([O-])([O-])(=O)=O
别名信息
- 中文别名 -
  • 硫酸锆
  • 硫酸锆Zirconium sulphate
  • 硫酸锆溶液
  • 四水硫酸锆
  • 正硫酸锆(酸式)
  • 硫酸锆(4+)(2:1)
- 英文别名 -
  • Zirconium sulphate
  • ZIRCONIUM SULFATE
  • disulfatozirconicacid
  • Wln: zr2 S-o4*2
  • Zirconium(IV) sulfate
  • ZIRCONIUM(IV)SULPHATE
  • zirconiumdisulfate
  • zirconiumorthosulfate
  • ZIRCONYLSULPHATE
  • Zirconiumsulfate (Zr(SO4)2) (6CI)
  • Blancorol ZB 33
  • Tanfix SZS
  • Zirconium sulfate (1:2)
  • Nsc115915
  • Zirconium disulfate
  • Zirconium orthosulfate
  • Zirconium(IV) sulfate solution
物化性质
实验特性
LogP -0.51440
PSA 177.28000
Merck 13,10235
熔点 410 ºC
溶解度 H2O: slightly soluble(lit.)
颜色与性状 不可用
溶解性 不可用
密度 3.22
计算特性
精确分子量 281.80800
氢键供体数量 0
氢键受体数量 8
可旋转化学键数量 0
重原子数量 11
复杂度 62.2
同位素原子数量 0
确定原子立构中心数量 0
不确定原子立构中心数量 0
确定化学键立构中心数量 0
不确定化学键立构中心数量 0
共价键单元数量 3
疏水参数计算参考值(XlogP)
互变异构体数量
表面电荷 0
安全信息
RTECS号 ZH9100000
安全术语 8
安全说明 S26-S27-S36/37/39-S45
包装等级 II
包装类别 II
风险术语 R34
危险等级 8
危险品标志 C C
危险品运输编号 UN 3264 8/PG 3
PackingGroup II
危险类别码 R34
TSCA Yes
HazardClass 8
海关数据
海关编码 2842909090
海关数据

中国海关编码:

2842909090
硫酸锆 MSDS
基础信息
Name: Zirconium sulfate tetrahydrate 99.99% Material Safety Data Sheet
Synonym: None Known
CAS: 14644-61-2
Section 1 - Chemical Product ? MSDS Name:Zirconium sulfate tetrahydrate 99.99% Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
14644-61-2 Zirconium sulfate tetrahydrate 99.99% 238-694-4
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary edema.
Chronic:
Effects may be delayed.

Section 4 - FIRST AID MEASURES
? Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Substance is nonflammable; use agent most appropriate to extinguish surrounding fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
? Handling:
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 14644-61-2: United States OSHA: 5 mg/m3 TWA (listed under Zirconium).
Belgium - TWA: (listed as zirconium): 5 mg/m3 VLE Belgium - STEL: (listed as zirconium): 10 mg/m3 VLE Malaysia: (listed as zirconium): 5 mg/m3 TWA Netherlands: (listed as zirconium): 5 mg/m3 MAC Russia: (listed as zirconium): 6 mg/m3 TWA Spain: (listed as zirconium): 5 mg/m3 VLA-ED Spain: (listed as zirconium): 10 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear chemical splash goggles. Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Crystalline powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 410 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: SOLUBLE IN WATER: 52.5 G/100G (18C)
Specific Gravity/Density: 3.2200g/cm3
Molecular Formula: O8S2Zr.4H2O
Molecular Weight: 355.39

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable under normal temperatures and pressures. Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
High temperatures, incompatible materials, dust generation, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, sulfuric acid.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 14644-61-2: ZH9100000 LD50/LC50:
CAS# 14644-61-2: Oral, rat: LD50 = 3500 mg/kg; Oral, rat: LD50 = 1235 mg/kg.
Carcinogenicity:
Zirconium sulfate tetrahydrate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
USA RQ: CAS# 14644-61-2: 5000 lb final RQ; 2270 kg final RQ

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 14644-61-2: No information available.
Canada
CAS# 14644-61-2 is listed on Canada's DSL List.
CAS# 14644-61-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 14644-61-2 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A
化合物详情(旧版)

SMILES

[Zr+4].O=S([O-])(=O)[O-].O=S([O-])(=O)[O-]

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