Phosphorus oxide (PO2)(6CI,7CI,8CI,9CI) | 12164-97-5
英文名称:
Phosphorus oxide (PO2)(6CI,7CI,8CI,9CI)
CAS No.:
12164-97-5
分子式:
HO2 P
分子量:
63.98054
名称和标识符
InChIKey
GQZXNSPRSGFJLY-UHFFFAOYSA-N
Inchi
InChI=1S/HO2P/c1-3-2/h(H,1,2)
SMILES
O=PO
别名信息
- 英文别名 -
Phosphorus oxide (PO2)(6CI,7CI,8CI,9CI)
Phosphorus dioxide
12164-97-5
CHEBI:37370
DTXSID60153329
dioxidophosphorus(.)
PO2(.)
phosphorus(IV) oxide
物化性质
实验特性
LogP
0.08820
PSA
34.14
沸点
°Cat760mmHg
闪点
°C
计算特性
精确分子量
63.97143
氢键供体数量
0
氢键受体数量
1
可旋转化学键数量
0
同位素质量
62.964
重原子数量
3
复杂度
7.5
同位素原子数量
0
确定原子立构中心数量
0
不确定原子立构中心数量
0
确定化学键立构中心数量
0
不确定化学键立构中心数量
0
共价键单元数量
1
疏水参数计算参考值(XlogP)
-0.7
拓扑分子极性表面积
18.1Ų
相关文献
1.
Selective and clean synthesis of aminoalkyl-H-phosphinic acids from hypophosphorous acid by phospha-Mannich reaction
Peter Urbanovsky,Jan Kotek,Ivana Císa?ová,Petr Hermann RSC Adv. 2020 10 21329
2.
Chemoselective synthesis of long-chain alkyl-H-phosphinic acids via one-pot alkylation/oxidation of red phosphorus with alkyl-PEGs as recyclable micellar catalysts
Vladimir A. Kuimov,Svetlana F. Malysheva,Natalia A. Belogorlova,Nina K. Gusarova,Boris A. Trofimov Org. Biomol. Chem. 2021 19 10587
3.
Insights into a surprising reaction: The microwave-assisted direct esterification of phosphinic acids
Gy?rgy Keglevich,Nóra Zsuzsa Kiss,Zoltán Mucsi,Tamás K?rtvélyesi Org. Biomol. Chem. 2012 10 2011
4.
Synthesis of benzyl sulfides via substitution reaction at the sulfur of phosphinic acid thioesters
Yoshitake Nishiyama,Takamitsu Hosoya,Suguru Yoshida Chem. Commun. 2020 56 5771
5.
Sequential catalytic role of bifunctional bicyclic guanidine in asymmetric phospha–Michael reaction
Bokun Cho,Choon-Hong Tan,Ming Wah Wong Org. Biomol. Chem. 2011 9 4550
6.
Design of a Br?nsted acid with two different acidic sites: synthesis and application of aryl phosphinic acid–phosphoric acid as a Br?nsted acid catalyst
N. Momiyama,T. Narumi,M. Terada Chem. Commun. 2015 51 16976
7.
Complexing properties of [(glycylamino)methyl]phosphinic acids towards Co2+, Ni2+, Cu2+ and Zn2+ ions in aqueous solutions
Michal Lukás?,Mojmír Kyvala,Petr Hermann,Ivan Lukes?,Daniele Sanna,Giovanni Micera J. Chem. Soc. Dalton Trans. 2001 2850
8.
Complexing properties of [(glycylamino)methyl]phosphinic acids towards Co2+, Ni2+, Cu2+ and Zn2+ ions in aqueous solutions
Michal Lukás?,Mojmír Kyvala,Petr Hermann,Ivan Lukes?,Daniele Sanna,Giovanni Micera J. Chem. Soc. Dalton Trans. 2001 2850
9.
Branched alkylphosphinic and disubstituted phosphinic and phosphonic acids: effective synthesis based on α-olefin dimers and applications in lanthanide extraction and separation
I. E. Nifant'ev,M. E. Minyaev,A. N. Tavtorkin,A. A. Vinogradov,P. V. Ivchenko RSC Adv. 2017 7 24122
10.
B(C6F5)3-catalyzed O–H insertion reactions of diazoalkanes with phosphinic acids
Yangyang Zhang,Xinzhi Zhang,Jincheng Zhao,Jun Jiang Org. Biomol. Chem. 2021 19 5772
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