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二苯二硫醚 | 882-33-7

二苯二硫醚
(phenyldisulfanyl)benzene
882-33-7
C12H10S2
218.337800502777
如需查看该化合物的详细结构式,mol文件,smile,InChi 请点击:二苯二硫醚结构式
13436
二苯二硫醚价格
简介
二苯二硫醚的英文名称为Phenyl disulfide,中文别名为二苯基二硫醚CAS号码为882-33-7,分子式无C12H10S2,分子量为218.34,属于高纯有机试剂,该物质可以用作农药、医药、染料中间体,通常对水是不危害的,若无政府许可,勿将材料排入周围环境。常温常压下稳定,避免氧化物接触保持容器密封,储存在阴凉,干燥的地方 。
名称和标识符
MDL MFCD00003065
InChIKey GUUVPOWQJOLRAS-UHFFFAOYSA-N
Inchi 1S/C12H10S2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10H
SMILES S(C1C=CC=CC=1)SC1C=CC=CC=1
BRN 639794
别名信息
- 中文别名 -
  • 二苯二硫醚
  • 二硫化二苯
  • 二苯基二硫
  • 二苯基二硫醚
  • 二苯基二硫化物
  • 二苯二硫
  • 苯二硫苯
  • Diphenyl Disulfide 二苯二硫醚
  • 苯硫酚二聚体(杂质E)
  • 二苯二硫醚 标准品
  • 奈非那韦相关化合物E USP标准品
  • 奈非那韦杂质E
- 英文别名 -
  • AKOS 94361
  • BIPHENYL DISULFIDE
  • DIPHENYL DISULFIDE
  • DIPHENYL DISULPHIDE
  • DIPHENYLDISULPIDE
  • FEMA 3225
  • PHENYL DISULFIDE
  • PHENYL DISULPHIDE
  • (Phenyldisulfanyl)benzene
  • Disulfide,diphenyl
  • dlphenyldisulfide
  • USAF e-1
  • phenyldithiobenzene
  • DIPHENTYL DISULFIDE
  • 1,1'-Dithiobisbenzene
  • 4,4'-Dithiobis(benzene)
  • Diphenyl persulfide
  • NSC 2689
  • disulfide diphenyl
  • 1,2-diphenyldisulfane
  • Disulfide, diphenyl
  • diphenyldisulfide
  • 1,1'-dithiodibenzene
  • Phenyldisulfide
  • diphenyldisulphide
  • FEMA No. 3225
  • Phenyl disulfide, 99%
  • 1,1'-disulfanediyldibenzene
  • MLS000069663
  • NSC2689
  • GUUVPOWQJOLRAS-UHFFFAOYSA-N
  • 7P54H519IJ
  • SMR000059177
  • phenyi
  • Phenyl Disulfide
  • Diphenyl disulfide
  • phenyl disulfide
  • Phenyl disulfide
  • Diphenyl disulfide (ACI)
  • Phenyl disulfide (8CI)
  • 1,1′-Dithiodibenzene
  • 1,2-Diphenyldisulfane
  • Biphenyl disulfide
  • Diphenyl disulphide
  • DPDS
  • Phenyl disulfide,99%
物化性质
实验特性
LogP 4.48600
PSA 50.60000
折射率 1,441-1,444
水溶性 Insoluble in water.
沸点 191-192 ºC
熔点 58-60 °C (lit.)
闪点 310°C
FEMA 3225 | PHENYL DISULFIDE
溶解度 xylene: soluble3%, clear, colorless to yellow
颜色与性状 白色粉末
稳定性 Stable. Incompatible with strong oxidizing agents, strong bases.
溶解性 溶于乙醇、苯和乙醚,不溶于水。
密度 1.353
计算特性
精确分子量 218.02200
氢键供体数量 0
氢键受体数量 2
可旋转化学键数量 3
同位素质量 218.022392
重原子数量 14
复杂度 128
同位素原子数量 0
确定原子立构中心数量 0
不确定原子立构中心数量 0
确定化学键立构中心数量 0
不确定化学键立构中心数量 0
共价键单元数量 1
疏水参数计算参考值(XlogP) 4.4
互变异构体数量
表面电荷 0
拓扑分子极性表面积 50.6
国际标准相关数据
EINECS 2689
海关数据
海关编码 2930909090
海关数据

中国海关编码:

2930909090

概述:

2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

申报要素:

品名, 成分含量, 用途

Summary:

2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

合成路线

合成路线:1 步

反应条件:
参考文献:
Carbonylative Synthesis of 3-Substituted Thiochromenones via Rhodium-Catalyzed [3 + 2 + 1] Cyclization of Different Aromatic Sulfides, Alkynes, and Carbon Monoxide
Zhu, Fengxiang; et al, Journal of Organic Chemistry, 2018, 83(21), 13612-13617

合成路线:1 步

反应条件:
参考文献:
Novel deoxygenation of thiosulfonates and sulfoxides with reduced iron
Fujisawa, Tamotsu; et al, Chemistry Letters, 1973, (12), 1241-2

合成路线:1 步

反应条件:
参考文献:
Study on improvement of diphenyl disulfide synthesis
Zhu, Bei-bei; et al, Gaoxiao Huaxue Gongcheng Xuebao, 2020, 34(4), 963-968

合成路线:1 步

反应条件:
参考文献:
Copper-Catalyzed Direct Thiolation of Ketones Using Sulfonohydrazides: A Synthetic Route to Benzylic Thioethers
Jadhao, Amardeep Ramprasad ; et al, Journal of Organic Chemistry, 2023, 88(19), 14078-14087

合成路线:1 步

反应条件:
参考文献:
Transformation of arylboronic acids with sodium thiosulfate into organodisulfides catalyzed by a recyclable polyoxometalate-based Cr(III) catalyst
Li, Huiyi; et al, Green Chemistry, 2021, 23(16), 6059-6064

合成路线:1 步

反应条件:
参考文献:
Efficient Cu-catalyzed one-pot odorless synthesis of sulfides from triphenyltin chloride, aryl halides and S8 in PEG
Rostami, Abed; et al, Tetrahedron Letters, 2016, 57(2), 192-195

合成路线:1 步

反应条件:
参考文献:
Synthesis of di(hetero)aryl sulfides by directly using arylsulfonyl chlorides as a sulfur source
Wu, Qian; et al, Chemical Communications (Cambridge, 2011, 47(32), 9188-9190

合成路线:1 步

反应条件:
参考文献:
Formation of sulfur-sulfur bonds by nucleophilic attack on sulfenyl halides and thiocyanates
Chaudri, Tanweer A., Pakistan Journal of Scientific and Industrial Research, 1976, 19(1), 1-3

合成路线:1 步

反应条件:
参考文献:
Reaction of α-keto sulfoxides with hydrogen chloride and trichloroacetic acid
Wakui, Toshimitsu; et al, Bulletin of the Chemical Society of Japan, 1978, 51(10), 3081-2

合成路线:1 步

反应条件:
参考文献:
A singular property of thioesters of acetic acid
Charonnat, Raymond; et al, Compt. rend., 1954, 238, 119-21

合成路线:1 步

反应条件:
参考文献:
Dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new S-donor for direct synthesis of symmetrical disulfides
Soleiman-Beigi, Mohammad; et al, Scientific Reports, 2022, 12(1),

合成路线:1 步

反应条件:
参考文献:
Deep Eutectic Solvents as Reaction Media for the Palladium-Catalysed C-S Bond Formation: Scope and Mechanistic Studies
Marset, Xavier; et al, Chemistry - A European Journal, 2017, 23(44), 10522-10526

合成路线:1 步

反应条件:
参考文献:
Aerobic Copper-Catalyzed Acetoxysulfenylation and Hydrosulfenylation of Alkenes with Thiols
Taniguchi, Nobukazu, ChemistrySelect, 2018, 3(22), 6209-6213

合成路线:1 步

反应条件:
参考文献:
Efficient deoxygenation of sulfoxides to thioethers and reductive coupling of sulfonyl chlorides to disulfides with tungsten hexachloride
Firouzabadi, Habib; et al, Synthesis, 1999, (3), 500-502

合成路线:1 步

反应条件:
参考文献:
Highly Chemoselective NH- and O-Transfer to Thiols Using Hypervalent Iodine Reagents: Synthesis of Sulfonimidates and Sulfonamides
Tota, Arianna; et al, Organic Letters, 2018, 20(9), 2599-2602

合成路线:1 步

反应条件:
参考文献:
Byproduct promoted regioselective sulfenylation of indoles with sulfinic acids
Liu, Cong-Rong; et al, Organic & Biomolecular Chemistry, 2015, 13(8), 2251-2254

合成路线:1 步

反应条件:
参考文献:
Copper-Catalyzed C-S Bond Formation via the Cleavage of C-O Bonds in the Presence of S8 as the Sulfur Source
Rostami, Abed; et al, Synthesis, 2017, 49(22), 5025-5038

合成路线:1 步

反应条件:
参考文献:
Copper-catalyzed synthesis of β-haloalkenyl chalcogenides by addition of dichalcogenides to internal alkynes and its application to synthesis of (Z)-tamoxifen
Taniguchi, Nobukazu, Tetrahedron, 2009, 65(14), 2782-2790

合成路线:1 步

反应条件:
参考文献:
Visible light-induced C-H sulfenylation using sulfinic acids
Sun, Pengfei; et al, Green Chemistry, 2017, 19(20), 4785-4791

合成路线:1 步

反应条件:
参考文献:
Synthesis of Thioethers and Thioesters with Alkyl Arylsulfinates as the Sulfenylation Agent under Metal-Free Conditions
Li, Yahui; et al, Chemistry - An Asian Journal, 2016, 11(24), 3503-3507

合成路线:1 步

反应条件:
参考文献:
Iodine-mediated thiolation of phenol/phenylamine derivatives and sodium arylsulfinates in neat water
Wang, Dingyi; et al, RSC Advances, 2015, 5(130), 108030-108033

合成路线:1 步

反应条件:
参考文献:
The direct synthesis of symmetrical disulfides and diselenides by metal-organic framework MOF-199 as an efficient heterogenous catalyst
Soleiman-Beigi, Mohammad; et al, RSC Advances, 2015, 5(106), 87564-87570

合成路线:1 步

反应条件:
参考文献:
Efficient Cu-catalyzed one-pot odorless synthesis of sulfides from triphenyltin chloride, aryl halides and S8 in PEG
Rostami, Abed; et al, Tetrahedron Letters, 2016, 57(2), 192-195

合成路线:1 步

反应条件:
参考文献:
Deoxygenation of sulfoxides and reductive coupling of sulfonyl chlorides, sulfinates, and thiosulfonates using Silphos [PCl3-n(SiO2)n] as a heterogeneous phosphine reagent
Iranpoor, Nasser; et al, Synlett, 2005, (9), 1447-1449

合成路线:1 步

反应条件:
参考文献:
Transition-Metal-Free Selective Synthesis of (Z)-1,2-Diarylthio-1-arylalkenes, (2-Arylethene-1,1,2-triyl)tris(arylsulfane)s and Alkynyl Sulfides from Thiocyanates and Terminal Arylalkynes
Yang, Lian; et al, ChemistrySelect, 2019, 4(1), 311-315

合成路线:1 步

反应条件:
参考文献:
Controllable and chemo-selective conversion of sodium sulfinates to disulfides or thiosulfonates by a solvent-free mechanochemical approach
Wang, Jinjing; et al, Tetrahedron, 2023, 139,
相关文献
专业数据库参考
PubChemId 13436
参考资料
Reaxys RN 639794
Beilstein 639794
化合物详情(旧版)

二苯二硫醚二苯二硫醚物理化学性质

【外观性状】白色粉末。熔点62-63

【熔点 】58-60 °C

【沸点 】191-192 °C (15 mmHg)

【密度 】1.353

FEMA 3225

【闪点 】310°C

BRN 639794

二苯二硫醚产品用途

用作农药、医药、染料中间体

二苯二硫醚应用领域

【用途一】用作农药、医药、染料中间体



二苯二硫醚常见问题列表

【毒性】GRAS(FEMA)。

【使用限量】FEMA:饮料、冷饮、糖果、凝胶制品、布丁,均1.0mg。



化学品安全说明书(MSDS)



储运特性





产品用途
用作农药、医药、染料中间体
二苯二硫醚推荐生产厂家
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